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Thermal Vibration in nAgI-3Ag2O-2V2O5 Glasses

Published online by Cambridge University Press:  15 February 2011

A. Thazin
Affiliation:
Department of Physics, Ibaraki University, Mito 310-8512, Japan
Y. Fujishima
Affiliation:
Department of Physics, Ibaraki University, Mito 310-8512, Japan
M. Arai
Affiliation:
Department of Physics, Ibaraki University, Mito 310-8512, Japan
T. Sakuma
Affiliation:
Department of Physics, Ibaraki University, Mito 310-8512, Japan
H. Takahashi
Affiliation:
Faculty of Engineering, Ibaraki University, Hitachi 316-8511, Japan
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Abstract

The X-ray diffraction measurement for superionic conducting glasses nAgI-3Ag2O-2V2O5 (n = 2, 5, 10) has been performed at 12, 100, 200 and 290 K. The temperature dependence of structure factor S(Q) of nAgI-3Ag2O-2V2O5 has been discussed based on the theoretical treatment including the thermal vibration of atoms in noncrystalline materials. The effective overall Debye-Waller temperature parameter B increases with the increase of temperature and also with AgI concentration.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

1. Waseda, Y., The structure of Non-Crystalline Materials (McGraw-Hill, New York, 1980).Google Scholar
2. Warren, B. E., X-ray Diffraction (Addison-Wesley, Reading, Mass., 1969).Google Scholar
3. Rajalakshmi, A., Seshasayee, M., Yamaguchi, T., Nomura, M. and Ohtaki, H., J. Non-Cryst. Solids 113, 260 (1989).Google Scholar
4. Patnaik, S., Rajalakshmi, A., Seshasayee, M. and Ohtaki, H., Solid State Ionics 59, 229 (1993).Google Scholar
5. Takahashi, H., Hiki, Y., Sakuma, T., Morii, Y., Solid State Ionics 90, 125128 (1996).Google Scholar
6. Takahashi, H., Shishitsuka, K., Sakuma, T., Shimojo, Y., Ishii, Y. Solid State Ionics 113-115, 685 (1998).Google Scholar
7. Malugani, J.P. and Mercier, R., Solid State Ionics 13, 293 (1984).Google Scholar
8. Minami, T., J. Non-Cryst. Solids 56, 15 (1986).Google Scholar
9. Sakuma, T., Aoyama, T., Tsuchiya, Y., J. Phys. Soc. Jpn. 64, 3770 (1995).Google Scholar
10. Thazin, A., Arai, M., Sakuma, T., Takahashi, H., Solid State Ionics 150, 291294 (2002).Google Scholar
11. Minami, T., Imazawa, K. and Tanaka, M., J. Non-Cryst. Solids 42, 469 (1980).Google Scholar
12. Waseda, Y., Novel Application of Anomalous (Resonance) X-ray Scattering for Structural Characterization of Disordered Materials, Springer-Verlag, Berlin, 1984.Google Scholar
13. Hoshino, S., Solid State ionics 48, 179 (1991).Google Scholar
14. Aniya, M., Solid State Ionics 136-137, 10851089 (2000).Google Scholar