Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-16T15:02:32.474Z Has data issue: false hasContentIssue false
  • English
  • Français

Thermal Properties and Crystallinity of Grafted Copolymer Networks containing a Crystallizable Poly(ε-caprolactone) Crosslinker in an aqueous environment

Published online by Cambridge University Press:  01 March 2012

Karl Kratz ,
Uttamchand Narendra Kumar ,
Ulrich Noechel  and
Andreas Lendlein
Karl Kratz
Affiliation:
Centre for Biomaterial Development and Berlin Brandenburg Centre for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
Uttamchand Narendra Kumar
Affiliation:
Centre for Biomaterial Development and Berlin Brandenburg Centre for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
Ulrich Noechel
Affiliation:
Centre for Biomaterial Development and Berlin Brandenburg Centre for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
Andreas Lendlein
Affiliation:
Centre for Biomaterial Development and Berlin Brandenburg Centre for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
Get access

Abstract

Here we introduce a multifunctional copolymer network system with adjustable thermomechanical properties, which is also capable to show a substantial water uptake and in this way should allow the additional alteration of the overall elastic properties besides the variation of the crosslinking density. The swelling capacity in water, the thermal properties as well as the crystallinity of a series of grafted copolymer networks named CLEG composed of water swellable poly(ethylene glycol) (PEG) side chains and crystallizable poly(ε-caprolactone) (PCL) segments acting as covalent crosslinker were explored in an aqueous environment.

The water swelling capability of the CLEG polymer networks was found to increase from 120% to 240% with increasing weight content of PEG. In contrast to the dry state, where two well separated melting temperatures could be observed for all CLEG samples, in aqueous environment only one melting temperature slightly above 40 °C, was obtained, whereby the overall crystallinity after swelling with water was strongly related to the PCL content in the CLEG polymer networks.

Keywords

polymerx-ray diffraction (XRD)crystalline
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1403: Symposium V – Multifunctional Polymer-Based Materials , 2012 , mrsf11-1403-v02-06
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Behl, M. and Lendlein, A., Journal of Materials Chemistry, 20, 3335 (2010).Google Scholar
2. Bellin, I., Kelch, S., Langer, R., and Lendlein, A., Proceedings of the National Academy of Sciences of the United States of America, 103, 18043 (2006).Google Scholar
3. Kumar, U.N., Kratz, K., Heuchel, M., Behl, M., and Lendlein, A., Advanced Materials, 23, 4157 (2011).Google Scholar
4. Lendlein, A., Schmidt, A.M., and Langer, R., Proceedings of the National Academy of Sciences of the United States of America, 98, 842 (2001).Google Scholar
5. Behl, M., Razzaq, M.Y., and Lendlein, A., Advanced Materials, 22, 3388 (2010).Google Scholar
6. Behl, M., Bellin, I., Kelch, S., Wagermaier, W., and Lendlein, A., Mater. Res. Soc. Symp. Proc., 1140, 3 (2009).Google Scholar
7. Kumar, U.N., Kratz, K., Wagermaier, W., Behl, M., and Lendlein, A., Journal of Materials Chemistry, 20, 3404 (2010).Google Scholar
8. Bellin, I., Kelch, S., and Lendlein, A., Journal of Materials Chemistry, 17, 2885 (2007).Google Scholar
9. Wagermaier, W., Zander, T., Hofmann, D., Kratz, K., Narendra Kumar, U., and Lendlein, A., Macromolecular Rapid Communications, 31, 1546 (2010).Google Scholar
10. Cui, J., Kratz, K., Hiebl, B., Jung, F., and Lendlein, A., Polymers for Advanced Technologies, 22, 126 (2011).Google Scholar
11. Discher, D.E., Janmey, P., and Wang, Y.L., Science, 310, 1139 (2005).Google Scholar
12. Ouasti, S., Donno, R., Cellesi, F., Sherratt, M.J., Terenghi, G., and Tirelli, N., Biomaterials, 32, 6456 (2011).Google Scholar
13. Fukuzaki, H., Yoshida, M., Asano, M., Kumakura, M., Mashimo, T., Yuasa, H., Imai, K., and Hidetoshi, Y., Polymer, 31, 2006 (1990).Google Scholar
14. Martuscelli, E., Silvestre, C., Addonizio, M.L., and Amelino, L., Die Makromolekulare Chemie, 187, 1557 (1986).Google Scholar