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Templated Assembly of Metal-Anion Arrays within Layered Hosts; Synthesis and Characterization of New Transition-Metal Oxyhalide Perovskites

Published online by Cambridge University Press:  01 February 2011

Gabriel Caruntu ,
Liliana Viciu ,
Leonard Spinu ,
Weilie Zhou  and
John B. Wiley
Gabriel Caruntu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Liliana Viciu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Leonard Spinu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Weilie Zhou
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
John B. Wiley
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
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Abstract

Ion exchange of Dion-Jacobson-type double- and triple-layered perovskites with divalent transition-metal halides leads to the templated assembly of metal-anion layers. A whole series of compounds of the form (MCl)LaNb2O7 (M = V, Cr, Mn, Fe, Co, Cu) and (CuCl)Ln2Ti2NbO10 (Ln = Pr, Nd, Sm, Eu) have been prepared. Additionally, a new series of host compounds is being developed to exploit this exchange chemistry; the new oxyfluorides, RbLnTiNbO6F (Ln = La, Pr, Nd) and RbLaM'NbO6F (M' = V4+, Mn4+, Nb4+, Mo4+), have been prepared by a direct route.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 718: Symposium D – Perovskite Materials , 2002 , D3.4
Copyright
Copyright © Materials Research Society 2002

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References

[1] Dion, M., Ganne, M., and Tournoux, M., Mater. Res. Bull., 16, 1429, (1981).Google Scholar
[2] Gopalakrishnan, J., Bhat, V., and Raveau, B., Mater. Res. Bull., 22, 413, (1987).Google Scholar
[3] Yoshimura, J., Ebina, Y., Kondo, J., Domen, K., and Tanaka, A., J. Phys. Chem., 97, 1970, (1993).Google Scholar
[4] Ruddlesden, S. and Popper, P., Acta Crystallogr., 10, 538, (1957).Google Scholar
[5] Wright, A. J. and Greaves, C., J. Mater. Chem., 6, 1823, (1996).Google Scholar
[6] Richard, M., Brohan, L., and Tournoux, M., J. Solid State Chem., 112, 345, (1994).Google Scholar
[7] Hyeon, K.-A. and Byeon, S.-H., Chem. Mater. 11, 352, (1999).Google Scholar
[8] Schaak, R. E. and Mallouk, T. E., J. Solid State Chem., 161, 225, (2001).Google Scholar
[9] Jacobson, A. J., Johnson, J. W., and Lewandowski, J. T., Inorg. Chem., 24, 3727, (1985).Google Scholar
[10] Ikeda, S., Tanaka, A., Shinohara, K., Hara, M., Kondo, J. N., Maruya, K. and Domen, K., Microporous Mater., 9, 253, (1997).Google Scholar
[11] Sato, M., Abo, J., Jin, T., and Ohta, M., J. Alloys Comp. 192, 81, (1993).Google Scholar
[12] Bednorz, J. G. and Müller, K. A. Z. Phys. B.: Condens. Matter. 64, 189, (1986).Google Scholar
[13] Dion, M., Ganne, M., Tournoux, M., and Ravez, J. Rev. Chim. Miner., 21, 92, (1984).Google Scholar
[14] Seshadri, R., Martin, C., Hervieu, M., Raveau, B., and Rao, C. N. R., Chem. Mater., 9, 270, (1997).Google Scholar
[15] Moritomo, Y., Asamitsu, A., Kuwahara, H., and Tokura, Y. Nature 380, 141, (1996).Google Scholar
[16] Kodenkandath, T. A., Lalena, J. N., Zhou, W. L., Carpenter, E. E., Sangregorio, C., Falster, A. U., Simmons, W. B., O'Connor, C. J., and Wiley, J. B., J. Am. Chem. Soc., 121, 10743, (1999).Google Scholar
[17] Kodenkandath, T. A., Kumbhar, A. S., Zhou, W. L. and Wiley, J. B. Inorg. Chem. 40, 710, (2001).Google Scholar
[18] Viciu, L., Caruntu, G., Royant, N., Koenig, J., Zhou, W. L., Kodenkandath, T. A., and Wiley, J. B., Inorg. Chem., in press.Google Scholar
[19] Caruntu, G., Spinu, L., and Wiley, J. B. Mater. Res. Bull., 37, 133, (2002).Google Scholar
[20] Choy, J.-H., Kim, J.-Y., Kim, S.-J., Sohn, J.-S., and Han, O. H., Chem. Mater. 13, 906, (2001).Google Scholar
[21] Bhuvanesh, N. S. P. and Gopalakrishnan, J. J. Mater. Chem. 7, 2297, (1997).Google Scholar