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Temperature-Dependent Electroluminescence from CdTe/CdS Solar Cells

Published online by Cambridge University Press:  01 February 2011

K. J. Price ,
A. Vasko ,
L. Gorrelland  and
A. D. Compaan
K. J. Price
Affiliation:
Summer faculty scholar from Morehead State University, Morehead, KY 40351 email address: [email protected]
A. Vasko
Affiliation:
Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606
L. Gorrelland
Affiliation:
Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606
A. D. Compaan
Affiliation:
Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606
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Abstract

Electroluminescence (EL) from polycrystalline CdTe/CdS solar cells was studied over the temperature range – 30 C to 25 C. We are able to observe above-background EL at forward current densities as low as 3 mA/cm2, allowing us to explore the EL behavior at current-voltage regimes within the normal operating parameters of the device. The EL spectrum is very similar to the photoluminescence (PL) spectrum, and is independent of applied voltage. We show that the EL most likely originates from injected electron-hole recombination at the CdTe/CdS junction. The total EL intensity is found to vary as a power-law function of current, EL ∼ Ib, where I is the forward current density and b is a constant. The value of b varies from sample to sample and decreases with increasing temperature. EL intensity typically is much more sensitive to device deterioration with light soak stress than is cell efficiency.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 763: Symposium B – Compound Semiconductor Photovoltaics , 2003 , B5.9
Copyright
Copyright © Materials Research Society 2003

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References

1. Wu, X., Keane, J.C., Dhere, R.G., DeHart, C., Albin, D.A., Duda, A., Gessert, T.A., Asher, S., Levi, D.H., and Sheldon, P., “16.5% Efficient CdS/CdTe Polycrystalline Thin-film Solar Cell,“ Proc. of 17th European Photovoltaic Solar Energy Conference. Munich, Germany, 22-26 Oct. 2001, pp 995–1000.Google Scholar
2. , Han, Wang, K., Yeh, C., Yang, L., Deng, X., and Roedern, B. Von, Phys. Rev. B 55, p.15619, (1997)Google Scholar
3. Potter, M.D.G.; Halliday, D.P.; Cousins, M.; Durose, K. Thin Solid Films, 361-362, p.248, (2000)Google Scholar
4. Compaan, A.D., Shvydka, D., Price, K.J, Vasko, A., and Karpov, V.G., Proceedings of the NCPV Program Review Meeting, September, 2001, Lakewood, CO.Google Scholar
5. Feldman, S.D., Seymour, F.H., Ohno, T.R., Kaydanov, V., and Collins, R.T., Proceedings of the 2003 NCPV Program Review, p. 199, (2003).Google Scholar
6. Feldman, Scott, Seymour, Fred, Ohno, Tim, Kaydanov, Victor, and Collins, Reuben, Proceedings of the Materials Research Society Spring Meeting, April 21-25, San Francisco, CA, to be published.Google Scholar
7. Grecu, D., Compaan, A. D., J. Appl. Phys., 87, p. 1722, (2000)Google Scholar
8. Wei, K., Pollack, F. H., Freeouf, J. L., Shvydka, D., Compaan, A. D., J. Appl. Phys., 85, p. 7418, (1999)Google Scholar
9. Shvydka, D., Compaan, A.D., and Karpov, V.G., ‘Nonlocal response in CdTe photovoltaics,’ J.Appl. Phys. 91, 9059 (2002).Google Scholar
10. Karpov, V.G., Compaan, A.D., and Shvydka, Diana, ‘Effects of nonuniformity in thin-film photovoltaics,’ Appl. Phys. Lett. 80, 4256 (2002).Google Scholar