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Temperature-Dependent Dynamics of Microconfined Cs2

Published online by Cambridge University Press:  10 February 2011

B. J. Loughnane
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
R. A. Farrer
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
L. A. Deschenes
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
J. T. Fourkas
Affiliation:
Eugene F. Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02167
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Abstract

Femtosecond optical-heterodyne detected Raman-induced Kerr effect spectroscopy (OHD-RIKES) has been used to study the reorientational dynamics of CS2 in microporous glasses over a wide range of temperatures. Microconfinement is shown to affect the behavior of the liquid at all the temperature studied. The results are interpreted in terms of a two-state model of the confined liquid.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

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