Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T00:45:35.515Z Has data issue: false hasContentIssue false
  • English
  • Français

TEM 3D Tomography of Noble Metal Nanowires Growth Inside SiO2 Mesoporous Aggregates

Published online by Cambridge University Press:  21 March 2011

J. Arbiol ,
E. Rossinyol ,
A. Cabot ,
F. Peirò ,
A. Cornet  and
J. R. Morante
J. Arbiol
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/ SCT, Universitat de Barcelona, Lluís Solé i Sabarís, 1-3, Barcelona, E-08028, (Spain)
E. Rossinyol
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/
A. Cabot
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/
F. Peirò
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/
A. Cornet
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/
J. R. Morante
Affiliation:
Enginyeria i Materials Electrònics, Departament d'Electrònica, Universitat de Barcelona, C/. Martíi Franqués, 1, Barcelona, E-08028, (Spain)[email protected], URL: http://nun97.el.ub.es/∼arbiol/
Get access

Abstract

The use of bright-field transmission electron microscopy 3-D tomographic reconstruction allowed us to localize the synthesized nanostructures within the pores of mesoporous nanotemplates. Using this technique, we found that noble metal impregnation resulted in the inclusion of metal nanostructures within the SBA-15 mesoporous silica hexagonal pores (from nanoclusters to nanowires). The method allowed corroborating if the nanostructures were synthesized inside the pores or if they were alternatively on the nanotemplate aggregates exterior surface.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 818: Symposium M – Nanoparticles and Nanowire Building Blocks-Synthesis, Processing, Characterization and Theory , 2004 , M4.5.1
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Joo, S.H., Choi, S.J., Oh, I., Kwak, J., Liu, Z., Terasaki, O. and Ryoo, R., Nature, 412, 169 (2001).Google Scholar
2. On, D. Trong, Desplantier-Giscard, D., Danumah, C. and Kaliaguine, S., Appl. Catal. A, 222, 299 (2001).Google Scholar
3. Kageyama, K., Tamazawa, J. and Aida, T., Science, 285, 2113 (1999).Google Scholar
4. Zhou, W., Thomas, J.M., Shephard, D. S., Johnson, B.F.G., Ozkaya, D., Maschmeyer, T., Bell, R. G. and Ge, Q., Science, 280, 705 (1998).Google Scholar
5. Cai, W., Zhang, Y., Jia, J. and Zhang, L., Appl. Phys. Lett., 73 (19), 2709 (1998).Google Scholar
6. Ryan, J.V., Berry, A.D., Anderson, M.L., Long, J.W., Stroud, R.M., Cepak, V.M., Browning, V.M., Rolison, D.R. and Merzbacher, C.I., Nature, 406, 169 (2000).Google Scholar
7. Arbiol, J., Cabot, A., Morante, J. R., Chen, F., and Liu, M., Appl. Phys. Lett., 81, 3449 (2002).Google Scholar
8. Cabot, A., Arbiol, J., Cornet, A., Morante, J. R., Chen, F., and Liu, M., Thin Solid Films, 436, 64 (2003).Google Scholar
9. Cabot, A., Arbiol, J., Rossinyol, E., Morante, J.R., Chen, F., and Liu, M., to be published in Electrochem. & Solid-State Lett. Google Scholar
10. Han, Y.-J., Kim, J. M. and Stucky, G. D., Chem. Mater., 12, 2068 (2000).Google Scholar
11. Wenchong, H., Dawei, G., Zhi, C., Liming, Y., Kozo, S., Craig, G. A., , Padmakar, K., Appl. Phys. Lett., 79, 3083 (2001).Google Scholar
12. Zhao, D., Huo, Q., Feng, J., Chmelka, B.F., Stucky, G.D., J. Am. Chem. Soc., 120, 6024 (1998).Google Scholar
13. Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G.H., Chmelka, B.F., Stucky, G.D., Science 279, 548 (1998).Google Scholar
14. Rosier, D. J. De and Klug, A., Nature, 217, 130 (1968).Google Scholar
15. Koster, A. J., Grimm, R., Typke, D., Hegrel, R., Stoschek, A., Walz, J. and Baumeister, W., J. Struct. Biol., 120, 276 (1997).Google Scholar
16. Koster, A. J., Ziese, U., Verkleij, A. J., Janssen, A. H. and Jong, K. P. de, J. Phys. Chem. B, 104, 9368 (2000).Google Scholar
17. Weyland, M., Topics in Catalysis, 21, 175 (2002).Google Scholar
18. Midgley, P. A., Weyland, M., Thomas, J. M. and B. Johnson, F. G., Chem. Commun., 907 (2001).Google Scholar
19. Arbiol, J., Rossinyol, E., Cabot, A., Peirò, F., Cornet, A., Morante, J.R., to be published in Electrochem. & Solid-State Lett. Google Scholar