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Tailored Interphases in Fibre Reinforced Polymers

Published online by Cambridge University Press:  21 February 2011

Michael R. Piggott
Michael R. Piggott*
Affiliation:
Advanced Composites Physics & Chemistry Group, Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario M5S IA4, Canada
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Abstract

The use of fibre coatings to enhance adhesion between fibres and polymers normally means that, in the fibre composite, some residue of the coating is present at the fibre-matrix interface. This constitutes the interphase. The mechanical properties of this material may be measured using simple fibre pull out tests. These tests have the advantage of revealing the interphase failure mode (i.e. brittle or ductile) as well as providing such data as work of fracture, yield stress, interfacial pressure and the coefficient of friction for post-debonding slip. Results obtained so far indicate some ductility and yielding with thermoplastic interphases, although final failure is brittle. Thermoset interphases appear to be universally brittle, with small works of fracture (10-200 Jm−2 ). The change in Young's modulus across the interphase may be a factor influencing brittle fracture, the biggest change giving the most brittle interphase.The ideal interphase should probably have a modulus intermediate between that of the fibre and the polymer, together with moderate yield stress, to give the composites adequate shear strength and good impact resistance through promotion of fibre pull outs.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 170: Symposium N – Interfaces in Composites , 1989 , 265
Copyright
Copyright © Materials Research Society 1990

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References

1. Plueddemann, E.P., Silane Coupling Agents (Plenum Press, New York 1982), Chapter 2Google Scholar
2. Harris, B., Beaumont, P.W.R., Ferran, E. M. de, J. Mater. Sci. 6, 238 (1971).Google Scholar
3. Plueddemann, E. P., 29th Ann. Tech. Conf. SPI Section 24A, (1974).Google Scholar
4. Hancox, N.L. and Wells, H., Fib. Sci. Tech. 10, 9 (1977)..Google Scholar
5. Tryson, L.D. and Kardos, J.L., 36th Ann. Conf., SPI, section 2E, (1981).Google Scholar
6. Crasto, A., Own, S.H. and Subramanian, R.V., Proc. ICCI., (Elsevier, New York, Ed., H., Ishida and J.L., Koenig, 1986), p. 133.Google Scholar
7. Sung, N.H., Jones, T.J. and Suh, N.P., J. Mater. Sci., 12, 239 (1977).Google Scholar
8. Piggott, M.R. and Reboredo, M., Proc. 34th Int. SAMPE Symp., 1913 (1989).Google Scholar
9. Kelly, A., Strong Solids, (Second edition; Clarendon Press, Oxford, 1973), p. 203.Google Scholar
10. Greszczuk, L.B., ASTM STP, 452, (1968), 42.Google Scholar
11. Piggott, M.R., Comp. Sci. Tech., 30, 295 (1987).Google Scholar
12. Penn, L.S. and Lee, S.M., Comp. Tech. Res. 11, 23 (1989).Google Scholar
13. Outwater, J.O. and Murphy, M.C., 24th Ann. Techn. Conf. SPI, Section 11C, (1969).Google Scholar
14. Chua, P.S. and Piggott, M.R., Comp. Sci. Tech. 22. 33 (1985).Google Scholar
15. Piggott, M.R. and Chua, P.S., Ind. Eng. Chem. Product, Res. Dev. 26, 672 (1987).Google Scholar
16. Benedetto, A.T. Di, Haddad, G., Schilling, C. and Osterholtz, F., Proc. Int. Conf. on Interfacial Phenomena in Composite Materials (Ed. F.R., Jones, Butterworths, London, 1989), p. 18 1.Google Scholar
17. Piggott, M.R., Advances in Composites: Chemical and Physicochemical Effects (Eds. Vigo, T.L. & Kinzig, B.J. Amer. Chem. Soc., 1989).Google Scholar
18. Piggott, M.R., J. Mater Sci. 13, 1709 (1978).Google Scholar
19. Kelly, A., Strong Solids (Second edition; Clarendon Press, Oxford, 1973), p. 180.Google Scholar
20. Piggott, M.R., Proc. ICF5, 465 (1981).Google Scholar
21. Metcalf, A.G. and Schmitz, K.G., ASTM Proc. 64, 1075 (1974).Google Scholar
22. Reboredo, M.; Monthly Report, University of Toronto, July 25, (1989).Google Scholar
23. Ishida, H., Polym. Comp. 5, 101 (1984).Google Scholar
24. Donnet, J.B., Dong, S., Guilpain, G. and Brendel, M., Proc. ICCI2 (Ed. H., Ishida, Elsevier, 1988), p 35.Google Scholar
25. Penn, L.S., Byerley, T.J. and Liao, T.K., Adhesion International (Proc. 10th Ann. Mtg. Adhesion Soc.) 631 (1987).Google Scholar
26. Piggott, M.R., Load Bearing Fibre Composites, (Pergamon, Oxford, 1980) Chapter 5.Google Scholar