Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-27T01:44:21.417Z Has data issue: false hasContentIssue false
  • English
  • Français

The Synthesis, Structure and Catalytic Properties of Some Aluminophosphate and Gallophosphate Materials Prepared Using Chiral Metal Complex Templates

Published online by Cambridge University Press:  10 February 2011

A. P. Wilkinson ,
M. J. Gray  and
S. M. Stalder
A. P. Wilkinson
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
M. J. Gray
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
S. M. Stalder
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
Get access

Abstract

The synthesis and crystal structure determination of d,l-Co(en)3.Ga3P4O16, xH2O (Pnna, a = 8.6502(9), b = 21.528(3), c = 13.717(2) Å) is described. This novel layered material contains Ga3P4O163- macroanions. The preparation and preliminary catalytic testing of a vanadium doped aluminophosphate that is isostructural with the gallophosphate is also discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 431: Symposium P – Microporous and Macroporous Materials , 1996 , 21
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Stinson, S.C., Chemical and Engineering News, October 9th, 44 (1995).Google Scholar
2. Davis, M.E. and Lobo, R.F., Chem.Mater. 4, 756 (1992).Google Scholar
3. Treacy, M.M.J. and Newsam, J.M., Nature 332, 249 (1988).Google Scholar
4. Newsam, J.M., Treacy, M.M.J., Koetsier, W.T. and de Gruyter, C.B., Proc.R.Soc.London A 420, 375 (1988).Google Scholar
5. Davis, M.E., Acc.Chem.Res. 26, 111 (1993).Google Scholar
6. Lok, B.M., Cannan, T.R. and Messina, C.A., Zeolites 3, 282 (1983).Google Scholar
7. Gilson, J-.P. in Zeolite Microporous Solids: Synthesis, Structure, and Reactivity, edited by E.G., Derouane, F., Lemos, C., Naccache and F.R., Ribeiro (Kluwer, Dordrecht, 1992), pp. 19.Google Scholar
8. Guth, J.L., Caullet, P., Seive, A., Patarin, J. and Delprato, F. in Guidelines for Mastering the Properties of Molecular Sieves, edited by D., Barthomeuf ( Plenum Press, New York, 1990), pp.69 Google Scholar
9. Balkus, K.J., Hargis, C.D. and Kowalak, S., ACS Symp.Ser. 499, 347 (1992).Google Scholar
10. Balkus, K.J., Kowalak, S., Ly, K.T. and Hargis, D.C., Stud.Surf.Sci.Catal. 69, 93 (1991).Google Scholar
11. Balkus, K.J., Gabrielov, A.G., Bell, S.L., Bedioui, F., Roue, L. and Devynck, J., Inorg.Chem. 33, 67 (1994).Google Scholar
12. Kowalak, S. and Balkus, K.J., Collect.Czech.Chem.Commun. 57, 774 (1992).Google Scholar
13. Rankel, L.A. and Valyocsik, E.W., U.S.Patent No. 4 500 503 (1985).Google Scholar
14. Bruce, D.A., Bertrand, J.A., Occelli, M.L., White, M.G. and Mertens, F. in Catalysis of Organic Reactions, edited by M.G., Scaros and M.L., Prunier ( Marcel Dekker, Inc., 1995), pp. 545.Google Scholar
15. Valyocsik, E.W., U.S.Patent No. 4 568 654 (1986).Google Scholar
16. Balkus, K.J. and Shepelev, S., Prepr.Pap.Am.Chem.Soc., Div.Petr. 38, 512 (1993).Google Scholar
17. Balkus, K.J., Gavrielov, A.G., Sandler, N. and Jacob, T., North American Catalysis Society, Snowbird, Utah, Meeting Abstracts, T115 (1995).Google Scholar
18. Balkus, K.J. and Kowalak, S., U.S.Patent No. 5 167 942 (1992).Google Scholar
19. Bruce, D.A., Wilkinson, A.P., Bertrand, J.A., White, M.G. and Edwards, J.C., manuscript in preparation.Google Scholar
20. Stalder, S.M. and Wilkinson, A.P., manuscript in preparation.Google Scholar
21. Bruce, D.A., Wilkinson, A.P., White, M.G. and Bertrand, J.A., J.Chem.Soc.Chem.Commun. 2059 (1995).Google Scholar
22. Bruce, D.A., Wilkinson, A.P., White, M.G. and Bertrand, J.A., J. Solid State Chem., in press.Google Scholar
23. Stalder, S.M. and Wilkinson, A.P. (unpublished results).Google Scholar
24. Dai, E.P., (private communication).Google Scholar
25. Bellusi, G. and Rigutto, M.S. in Studies in Surface Science and Catalysis, Vol. 85. Advanced Zeolite Science and Applications, edited by J.C., Jansen, M., Stocker, H.G., Karge and J., Weitkamp ( Elsevier Science, 1994), pp. 177.Google Scholar
26. Angelici, R.J., Synthesis and Technique in Inorganic Chemistry, Saunders, Philadelphia,1969), pp. 66.Google Scholar
27. Venkatathri, N., Hegde, S.G. and Sivasanker, S., J.Chem.Soc.Chem.Commun. 151 (1995).Google Scholar
28. Morgan, K., Gainsford, G. and Milestone, N., J.Chem.Soc.Chem.Commun. 425 (1995).Google Scholar
29. Oliver, S., Kuperman, A., Lough, A., Ozin, G.A., Garces, J.M., Olken, M.M. and Rudolf, P., Stud.Surf.Sci.Catal. 84, 219 (1994).Google Scholar
30. Kuperman, A., Nadimi, S., Oliver, S., Ozin, G.A., Garces, J.M. and Olken, M.M., Nature 365, 239 (1993).Google Scholar
31. Barrett, P.A. and Jones, R.H., J.Chem.Soc.Chem.Commun. 1979 (1995).Google Scholar
32. Thomas, J.M., Jones, R.H., Xu, R., Chen, J., Chippindale, A.M., Natarajan, S. and Cheetham, A.K., J.Chem.Soc.Chem.Commun. 929 (1992).Google Scholar
33. Chippindale, A.M., Natarajan, S., Thomas, J.M. and Jones, R.H., J.Solid State Chem. 111, 18 (1994).Google Scholar
34. Jones, R.H., Chippindale, A.M., Natarajan, S. and Thomas, J.M., J.Chem.Soc.Chem.Commun. 565 (1994).Google Scholar
35. Jones, R.H., Thomas, J.M., Xu, R., Huo, Q., Cheetham, A.K. and Powell, A.V., J.Chem.Soc.Chem.Commun. 1266 (1991).Google Scholar