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The Synthesis, Structure and Catalytic Properties of Some Aluminophosphate and Gallophosphate Materials Prepared Using Chiral Metal Complex Templates

Published online by Cambridge University Press:  10 February 2011

A. P. Wilkinson ,
M. J. Gray  and
S. M. Stalder
A. P. Wilkinson
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
M. J. Gray
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
S. M. Stalder
Affiliation:
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332
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Abstract

The synthesis and crystal structure determination of d,l-Co(en)3.Ga3P4O16, xH2O (Pnna, a = 8.6502(9), b = 21.528(3), c = 13.717(2) Å) is described. This novel layered material contains Ga3P4O163- macroanions. The preparation and preliminary catalytic testing of a vanadium doped aluminophosphate that is isostructural with the gallophosphate is also discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 431: Symposium P – Microporous and Macroporous Materials , 1996 , 21
Copyright
Copyright © Materials Research Society 1996

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