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Synthesis of SBA-16 Supported Catalyst for CNTs and Dispersion Study of CNTs in Polypyrrole Composite

Published online by Cambridge University Press:  19 December 2014

Tajamal Hussain ,
Adnan Mujahid ,
Khurram Shehzad ,
Asma Tufail Shah  and
Rehana Kousar
Tajamal Hussain*
Affiliation:
Institute of Chemistry, University of the Punjab. Lahore-54590, Pakistan
Adnan Mujahid
Affiliation:
Institute of Chemistry, University of the Punjab. Lahore-54590, Pakistan
Khurram Shehzad
Affiliation:
Center for Nano and Micro Mechanics, Tsinghua University, Beijing-100084, China
Asma Tufail Shah
Affiliation:
Interdisciplinary Research Centre in Biomedical Materials, COMSATS Institute of Information Technology, Lahore-54000, Pakistan
Rehana Kousar
Affiliation:
Institute of Chemistry, University of the Punjab. Lahore-54590, Pakistan
*
*E-mail: [email protected]
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Abstract

In last two decades, huge amount of research work has been contributed in the field of nanochemistry particularly for synthesis, characterization and applications of carbon nanotubes (CNTs). For synthesis of CNTs through chemical vapor deposition (CVD), supported metal catalyst is used preferentially. In view of that, SBA-16 supported nanoprticles of Iron, Fe/SBA-16, were prepared. To have Fe/SBA-16, adsorption of Fe nanoparticles on SBA-16 have been accomplished by reduction of ferrous ion on the surface of SBA-16. Afterwards, CNTs were synthesized by CVD using benzene as precursor over Fe/SBA-16 nanocatalyst. Synthesis of CNTs was carried out at 750°C with ambient pressure. Synthesized CNTs were functionalized by treating the them with a mixture of H2SO4/HNO3. As a result of this acidic treatment, carboxylic functional group was introduced on the surface of CNTs due to oxidation. As such prepared and functionalized CNTs were, further, used as filler in the synthesis of polymer nanocomposites of polypyrrol(PPY), matrix. These nanocomposites were prepared by in situ polymerization. Thus, electrical conductivity is measured for both types of polymer composites. On their comparison, important information regarding dispersion of CNT in the matrix are extracted.

Keywords

adsorptionchemical vapor deposition (CVD) (deposition)composite
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1752: Symposium MM – Carbon Nanotubes—Synthesis, Properties, Functionalization, and Applications , 2014 , pp. 95 - 100
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Makris, T. D., L Giorgi, , Giorgi, R, Lisi, N, and Salernitano, E, “CNTs Growth on Alumina Supported Nickel Catalyst by Thermal Cvd”, Diamond and related materials 14 815–19 (2005).CrossRefGoogle Scholar
Liu, H., Takagi, D., Chiashi, S., and Homma, Y., “The Growth of Single-Walled Carbon Nanotubes on a Silica Substrate without Using a Metal Catalyst”, Carbon 48 114–22 (2010).CrossRefGoogle Scholar
Ni, L., Kuroda, K., Zhou, L-P., Kizuka, T., Ohta, K., Matsuishi, K., and Nakamura, J., “Kinetic Study of Carbon Nanotube Synthesis over Mo/Co/Mgo Catalysts”, Carbon 44 2265–72 (2006).CrossRefGoogle Scholar
Landois, P., Peigney, A., Laurent, C., Frin, L, Datas, L., and Flahaut, E., “CcVD Synthesis of Carbon Nanotubes with W/Co–Mgo Catalysts”, Carbon 47 789–94 (2009).CrossRefGoogle Scholar
Du, H., Wang, C., Hsu, H., Chang, S., Yen, S., Chen, L., Viswanathan, Balasubramanian, and Chen, Kuei-Hsien, “High Performance of Catalysts Supported by Directly Grown Ptfe-Free Micro-Porous CNTs Layer in a Proton Exchange Membrane Fuel Cell”, Journal of Materials Chemistry 21 2512–16 (2011).CrossRefGoogle Scholar
Carta, D., Bullita, S., Falqui, A., Casula, M. F., Corrias, A., and Kónya, Z., “Carbon Nanotubes Synthesis over Feco-Based Catalysts Supported on Sba-16”, Nanopages 8 1–8 (2013).CrossRefGoogle Scholar
Solhy, A., Machado, B. F., Beausoleil, J., Kihn, Y., Gonçalves, F., Pereira, M. F. R., Órfão, J. J. M, Figueiredo, J. L., Faria, J. L., and Serp, P, MwCNTs Activation and Its Influence on the Catalytic Performance of Pt/MwCNTs Catalysts for Selective Hydrogenation', Carbon 46 1194–207 (2008).CrossRefGoogle Scholar
Shehzad, K., Ahmad, M. N., Hussain, T., Mumtaz, M., Shah, A. T., Mujahid, A., Wang, C., Ellingsen, J. and Dang, Z., “Influence of Carbon Nanotube Dimensions on the Percolation Characteristics of Carbon Nanotube/Polymer Composites”, Journal of Applied Physics, 116 064908 (2014).CrossRefGoogle Scholar
Dang, Z., Shehzad, K., Zha, J., Mujahid, A., Hussain, T., Nie, J. and Shi, C., “Complementary Percolation Characteristics of Carbon Fillers Based Electrically Percolative Thermoplastic Elastomer Composites”, Composites Science and Technology, 72 28–35 (2011).CrossRefGoogle Scholar
Dang, Z., Shehzad, K., Zha, J., Hussain, T., Jun, N., and Bai, J., “On Refining the Relationship between Aspect Ratio and Percolation Threshold of Practical Carbon Nanotubes/Polymer Nanocomposites”, Japanes Journal of Applied Physics, 50 080214–14-3(2011).CrossRefGoogle Scholar
Mi, Hongyu, Zhang, Xiaogang, Xu, Youlong, and Xiao, Fang, “Synthesis, Characterization and Electrochemical Behavior of Polypyrrole/Carbon Nanotube Composites Using Organometallic-Functionalized Carbon Nanotubes”, Applied Surface Science, 256 2284–88 (2010).CrossRefGoogle Scholar