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The Synthesis of Hybrid Materials by the Blending of Polyhedral Oligosilsesquioxanes into Organic Polymers

Published online by Cambridge University Press:  01 February 2011

Rusty L. Blansky ,
Shawn H. Phillips ,
Kevin Chaffee ,
Joseph Lichtenhan ,
Andre Lee  and
Hei Ping Geng
Rusty L. Blansky
Affiliation:
Air Force Research Laboratory, AFRL/PRSM 10 E. Saturn Blvd. Edwards AFB, CA 93524.
Shawn H. Phillips
Affiliation:
Air Force Research Laboratory, AFRL/PRSM 10 E. Saturn Blvd. Edwards AFB, CA 93524.
Kevin Chaffee
Affiliation:
Air Force Research Laboratory, AFRL/PRSM 10 E. Saturn Blvd. Edwards AFB, CA 93524.
Joseph Lichtenhan
Affiliation:
Air Force Research Laboratory, AFRL/PRSM 10 E. Saturn Blvd. Edwards AFB, CA 93524. Current Address: Hybrid Plastics, Fountain Valley CA 92708
Andre Lee
Affiliation:
Department of Materials Science and Engineering Rm 3514 Engineering Bldg. East Lansing, MI 48824.
Hei Ping Geng
Affiliation:
Department of Materials Science and Engineering Rm 3514 Engineering Bldg. East Lansing, MI 48824.
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Abstract

The study of organic/inorganic hybrid materials has become an increasingly widespread research focus. The advantage derived from such materials is the combining of two very different compounds which may result in something that bridges the performance gap between the two systems. We have previously reported such hybrid systems prepared by incorporating polyhedral oligosilsesquioxanes (POSS™) into traditional organic polymers by the copolymerization of POSS™ monomers and organic monomers. This presentation will discuss a more convenient method of incorporating POSS™ into a polymer: the blending of POSS™ into organic polymers. The research discussion will focus on the development of the POSS™ macromers used in our studies as well as the POSS™ polymer blends synthesized. One important property enhancement observed is the increase in surface hardness for a POSS™/poly styrene sample.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC6.2
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

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