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Synthesis of Epitaxial Thin-Films of Tetragonal Perovskites Via a Solution Technique

Published online by Cambridge University Press:  16 February 2011

David B. Beach ,
Jonathan S. Morrell ,
Ziling B. Xue  and
Eliot D. Specht
David B. Beach
Affiliation:
Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6197, [email protected]
Jonathan S. Morrell
Affiliation:
Department of Chemistry, University of Tennessee, Knoxville, TN
Ziling B. Xue
Affiliation:
Department of Chemistry, University of Tennessee, Knoxville, TN
Eliot D. Specht
Affiliation:
Metal and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN
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Abstract

Solution chemistry has been used to synthesize epitaxial films of SrLaGaO4, SrPrGaO4, SrLaAlO4, and SrPrAlO4 on single crystal substrates of [100] SrTiO3 and [100] LaAlO3. Precursor solutions were prepared from metal methoxyethoxides in 2-methoxyethanol. Films were prepared by spin-casting from partially hydrolyzed solutions followed by firing for 20 minutes in air at 850°C. The structure of the films was determined using X-ray diffraction. Theta/2-theta scans and omega scans (rocking curves) indicated that the films were c-axis aligned. Phi scans proved that the films were also aligned in-plane.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 547: Symposium DD – Solid-State Chemistry of Inorganic Materials II , 1998 , 303
Copyright
Copyright © Materials Research Society 1999

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References

1. Pajaczkowska, A., and Gloubokov, A., Prog. Crystal Growth and Charact., 36, 123 (1998).Google Scholar
2. Marks, T. J., Belot, J. A., Hinds, B. J., Chen, J., Studebaker, D., Lei, J., Chang, R. P. H., Schindler, J. L., and Kannewurf, C. R., Mat. Res. Soc. Symp. Proc., 415, 67 (1996).Google Scholar
3. Belot, J. A., Hinds, B. J., Chen, J., Wang, Y. Y., Dravid, V., and Marks, T. J., Chem. Vap. Deposition, 3(2), 78 (1997).Google Scholar
4. Lange, F. F., Science, 273, 903 (1996).Google Scholar
5. Budd, K. D., Dey, S. K., and Payne, D. A., Brit. Ceram. Proc., 36, 107 (1985).Google Scholar
6. Brown, L. M., and Mazdiyansi, K. S., Inorg. Chem., 9, 2783 (1970).Google Scholar