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Synthesis and Properties of Lanthanide-Exchanged Preyssler's Heteropolyanions

Published online by Cambridge University Press:  15 February 2011

Mark R. Antonio ,
J. Malinsky  and
L. Soderholm
Mark R. Antonio
Affiliation:
Chemistry Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439–4831, USA
J. Malinsky
Affiliation:
Chemistry Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439–4831, USA
L. Soderholm
Affiliation:
Chemistry Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439–4831, USA
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Abstract

Na+ in the Preyssler heteropolytungstate anion [NaP5W30O110]14− can be exchanged for a trivalent lanthanide ion. The potential significance of this new class of lanthanide heteropolyanions relates to their applications in catalysis science. This view follows from the fact that Keggin heteropolyanions and their free acids are used as heterogeneous solid catalysts and homogeneous solution catalysts. We describe synthetic conditions that lead to the incorporation of Ce3+ and Pr3+ within the Preyssler anion, and the coprecipitation of Ce3+ and the Preyssler anion. Initial studies indicate that the latter, coprecipitated, material deserves study for bifunctional catalytic activity.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 368: Symposium T – Synthesis and Properties of Advanced Catalytic Materials , 1994 , 223
Copyright
Copyright © Materials Research Society 1995

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