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The Synthesis and Characterization of Polybenzamides Containing Siloxanes.

Published online by Cambridge University Press:  26 February 2011

Robert J. Kumpf  and
Bernard Gordon III
Robert J. Kumpf
Affiliation:
Polymer Science Program, Department of Materials Science and Engineering, The Pennsylvania State University
Bernard Gordon III*
Affiliation:
Polymer Science Program, Department of Materials Science and Engineering, The Pennsylvania State University
*
**To whom correspondence should be addressed
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Abstract

Three different kinds of siloxane-containing polybenzamide copolymers have been prepared: a series of siloxane-containing segmented copolymers; a siloxane-poly(benzamide) random copolymer; and a poly(benzamide) - poly(dimethylsiloxane) block copolymer. The structures of these copolymers were confirmed using diffuse reflectance FTIR spectroscopy. Dilute solution viscometery showed them to be high polymers. The thermal stabilities of these copolymers were studied using thermal gravimetric analysis. Incorporation of siloxane units via a phenyl link was found to not affect the inherent thermal stability of the poly(benzamide) chain. The solution phase behavior of these copolymers in DMAC/LiCl was studied using an optical microscope fitted with cross-polars. The segmented copolymers and the block copolymer exhibited lyotropic behavior, which was influenced by the amount of siloxane and the overall molecular architecture. Solutions of the random copolymer were isotropic at all concentrations studied.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 134: Symposium J – Materials Science and Engineering of Rigid-Rod Polymers , 1988 , 153
Copyright
Copyright © Materials Research Society 1989

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Footnotes

*

Current Address: Central Research, Bayer AG, D4150 Krefeld- Uerdingen, Federal Republic of Germany

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