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Synthesis and Characterization of Electropolymerized Porphyrin Nanofibers

Published online by Cambridge University Press:  01 February 2011

Michael G. Walter  and
Carl C. Wamser
Michael G. Walter
Affiliation:
[email protected], Portland State University, Chemistry, P. O. Box 751, Portland, OR, 97207-0751, United States
Carl C. Wamser
Affiliation:
[email protected], Portland State University, Chemistry, P. O. Box 751, Portland, OR, 97207-0751, United States, 503-725-4261, 503-725-9525
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Abstract

Electrochemical oxidation of tetrakis-5,10,15,20-(4-aminophenyl)porphyrin (TAPP) on fluorine-doped tin oxide electrodes leads to a conductive polymeric film (poly-TAPP) with a nanostructured fibrous morphology. The nanofiber structure and growth rate are enhanced by the addition of pyridine (5 - 15%) to the dichloromethane electrochemical solution. Electropolymerization in the absence of pyridine leads to a more highly bundled poly-TAPP structure with a spectrum indicative of protonated porphyrin units. Testing of poly-TAPP electrodes in an electrochemical iodide cell and in a 1-(3-methoxycarbonyl)propyl-1-phenyl[6,6]C61 (PCBM) integrated solid state photovoltaic cell indicates modest photoactivity.

Keywords

electrochemical synthesispolymerizationphotovoltaic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1013: Symposium Z – Organic and Nanoparticle Hybrid Photovoltaic Devices , 2007 , 1013-Z04-07
Copyright
Copyright © Materials Research Society 2007

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References

1. Kadish, K. M., Smith, K. M., Guilard, R., The Porphyrin Handbook. (Academic Press: San Diego, 2000).Google Scholar
2. White, B. A., Murray, R. W., J. Electroanal. Chem. 189(2), 345–352 (1985).Google Scholar
3. Plieth, W., Bund, A., Rammelt, U., Neudeck, S., Duc, L., Electrochim. Acta 51 (11), 2366–2372 (2006).Google Scholar
4. Bettelheim, A., White, B. A., Raybuck, S. A., Murray, R. W., Inorg. Chem., 26, 1009–1017 (1987).Google Scholar
5. Savenije, T. J., Koehorst, R. B. M., Schaafsma, T. J., Chem. Phys. Lett., 244, 363–370 (1995).Google Scholar
6. Weinkauf, J. R., Cooper, S. W., Schweiger, A., Wamser, C. C., J. Phys. Chem. A, 107 (18), 3486–3496 (2003).Google Scholar
7. Savenije, T. J., Koehorst, R. B. M., Schaafsma, T. J., J. Phys. Chem. B, 101, 720–725 (1997).Google Scholar