Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-25T15:21:51.614Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of Bimetallic Pd-Co Nano Magnetic Materials in Mesoporous Silica

Published online by Cambridge University Press:  15 March 2011

Balaji Tatineni ,
Dhananjay Kumar ,
Joslyn Perkins ,
Sergey Yarmolenko  and
Debasish Kuila
Balaji Tatineni
Affiliation:
Department of Chemistry, North Carolina A & T State University, Greensboro, NC 27411
Dhananjay Kumar
Affiliation:
Center for Advanced Materials and Smart Structures (CAMSS), North Carolina A & T State University, Greensboro, NC 27411
Joslyn Perkins
Affiliation:
Department of Chemistry, North Carolina A & T State University, Greensboro, NC 27411
Sergey Yarmolenko
Affiliation:
Center for Advanced Materials and Smart Structures (CAMSS), North Carolina A & T State University, Greensboro, NC 27411
Debasish Kuila
Affiliation:
Department of Chemistry, North Carolina A & T State University, Greensboro, NC 27411
Get access

Abstract

An one-pot procedure was developed for the synthesis of mesoporous silica containing bimetallic PdCo using Pd(NO3)2 and CoCl2, and cetyl trimethyl ammonium bromide (CTAB) as the templating agent, and tetramethoxy silane (TMOS) as the precursor. The materials were characterized using high resolution scanning transmission electron microscopy (HRSTEM), elemental analysis, X-ray diffraction (XRD), and magnetic measurements. The data indicate that the bimetallic Pd-Co nanoparticles are uniformly distributed on the inner pore walls of silica. The magnetic measurements of reduced Pd-Co nanoparticles (4-5 nm) in mesoporous silica reveal a typical ferromagnetic behavior up to 20 K and exhibit superparamagnetic properties above 30 K.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1118: Symposium K – Magnetic Nanostructures by Design , 2008 , 1118-K02-09
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCE

1. Scott, B.J., Wirnsberger, G., Stucky, G.D., Chem. Mater. 2001, 13, 3140.Google Scholar
2. Yang, H., Lu, Q., Gao, F., Shi, Q., Yan, Y., Zhang, F., Xie, S., Tu, B., Zhao, D., Adv. Funct. Mater. 2005, 15, 1377.Google Scholar
3. Toshima, N., Wang, Y., Chem. Lett. 1993, 1611.Google Scholar
4. Yonezawa, T., Toshima, N., J. Mol. Catal. 1993, 18, 167.Google Scholar
5. Panpranot, J., Goodwin, J. G. and Sayari, A., Catal. Today, 2002, 77, 269.Google Scholar
6. Johnson, B.F.G., Raynor, S.A., Brown, D.B., Shephard, D.S., Maschmeyer, T., Thomas, J.M., Hermans, S., Raja, R. and Sankar, G., J. Mol. Catal. A: Chem. 2002, 182, 89.Google Scholar
7. Iwasa, N., Masuda, S., Ogawa, N. and Takezawa, N., Appl. Catal. 125(1995)145.Google Scholar
8. Shephard, D.S., Maschmeyer, T., Sankar, G., Thomas, J.M., Ozkaya, D., Johnson, B.F.G., Raja, R., Oldroyd, R.D. and Bell, R.G., Chem-Eur. J., 1998, 4,1214.Google Scholar
9. Balaji, T., El-Safty, S. A., Hanaoka, T., Matsunaga, H., Mizukami, F., Angew. Chem. Int. Ed., 2006, 45, 7202.Google Scholar
10. Zhang, L., Shi, J., Yu, J., Hua, Z., Zhao, X., Ruan, M., Adv. Mater. 2002, 14, 1510.Google Scholar
11. Zhu, K., Yue, B., Zhou, W., He, H., Chem, Commun. 2003, 98.Google Scholar
12. Gao, F., Lu, Q., Liu, X., Yan, Y., Zhao, D., Nano Lett. 2001, 1, 743.Google Scholar
13. Zhu, K., He, H., Xie, S., Zhang, X., Zhou, W., Jin, S., Yue, B.. Chem. Phys. Lett. 2003, 377, 317.Google Scholar
14. King, N.C., Blackley, R.A., Wears, M.L., Newman, D.M., Zhou, W., Bruce, D.W., Chem. Commun. 2006, 3414–3416.Google Scholar
15. Balaji, T., Sasidharan, M., Matsunaga, H., Analyst, 2005, 130, 1162.Google Scholar
16. Zhang, Z., Dai, S., Blom, D.A., Shen, J., Chem. Mater. 2002, 14, 965.Google Scholar
17. Attard, G.S., Glyde, J.C., Goltner, C.G., Nature, 1995, 378, 366.Google Scholar
18. Vondrova, M., Majsztrik, P.W., Gould, S., Bocarsly, A.B., Chem. Mater. 2005, 17, 4755.Google Scholar
19. Vondrova, M., Klimczuk, T., Miller, V.L., Kirby, B.W., Yao, N., Cava, R.J., Bocarsly, A.B., Chem. Mater. 2005, 17, 6216.Google Scholar
20. Corain, B., Schmiid, G., Toshima, N., “Metal Nanoclusters in Catalysis and Materials Science” Elsevier, 2008.Google Scholar