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Synthesis and Characterization of Antimony-Doped Tin Oxide Nanophase materials for Electrochromic Applications

Published online by Cambridge University Press:  10 February 2011

J. Liu ,
J. P. Coleman  and
P. Madhukar
J. Liu
Affiliation:
Monsanto Corporate Research, Monsanto, 800 N. Lindbergh Blvd., St. Louis, MO 63167
J. P. Coleman
Affiliation:
Growth Enterprise Division, Monsanto, 800 N. Lindbergh Blvd., St. Louis, MO 63167
P. Madhukar
Affiliation:
Growth Enterprise Division, Monsanto, 800 N. Lindbergh Blvd., St. Louis, MO 63167
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Abstract

Antimony-doped tin oxide (ATO) nanophase materials containing up to 43 mole% antimony have been synthesized by a wet-chemistry method. These ATO materials exhibit enhanced electrochromic properties for display devices. The performance of the display devices is related to the nanostructure of the synthesized ATO materials. The average sizes of the ATO nanocrystallites depend on dopant level, annealing conditions, and synthesis processes. Antimony inhibits the growth of tin dioxide nanocrystallites during annealing at moderate temperatures. At higher annealing temperatures, however, antimony segregates to form separate oxide phases and ATO nanocrystallites grow significantly. A systematic study of the structural evolution of the synthesized ATO materials is presented and the relationship between the nanostructure of the ATO materials and the enhanced performance of the corresponding electrochromic devices is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 501: Symposium FF – Surface Controlled Nanoscale Materials for High-Added… , 1997 , 47
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1. Mortimer, R. J., Chem. Soc. Rev. 26, p147 (1997)Google Scholar
2. Granqvist, C. G., Solar Energy Materials and Solar Cells 32, p36 9 (1994).Google Scholar
3. Orel, B., Lavrencic-Stangar, U. and Kalcher, K., J. of Electrochem. Soc. 141, pL27 (1994).Google Scholar
4. Coleman, J. P., Lynch, A. T., Madhukar, P. and Wagenknecht, J. H., Solar Energy Materials and Solar Cells, in press (1997).Google Scholar
5. Cox, P.A., Egdell, R. G., Harding, C., Patterson, W. R. and Tavener, P. J., Surface. Science 123, p179 (1982).Google Scholar
6. Berry, F.J. and Smith, D.J., J. of Catalysis 88, p107 (1984).Google Scholar
7. Pyke, D. R., Reid, R. and Tilley, R. J., J. of Chem. Soc., Faraday Trans. 176, p1174 (1980).Google Scholar