Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-23T15:56:10.138Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface Passivated Air and Moisture Stable Mixed Zirconium Aluminum Metal-Hydride Nanoparticles

Published online by Cambridge University Press:  01 February 2011

Albert Epshteyn ,
Joel B. Miller ,
Katherine A. Pettigrew ,
Rhonda M. Stroud  and
Andrew P. Purdy
Albert Epshteyn
Affiliation:
[email protected], Naval Research Laboratory, Chemistry Division,, 4555 Overlook Ave., SW, Washington, DC, 20375, United States
Joel B. Miller
Affiliation:
[email protected], Naval Research Laboratory, Chemistry Division,, 4555 Overlook Ave., SW, Washington, DC, 20375, United States
Katherine A. Pettigrew
Affiliation:
[email protected], Naval Research Laboratory, Chemistry Division,, 4555 Overlook Ave., SW, Washington, DC, 20375, United States
Rhonda M. Stroud
Affiliation:
[email protected], Naval Research Laboratory, Chemistry Division,, 4555 Overlook Ave., SW, Washington, DC, 20375, United States
Andrew P. Purdy
Affiliation:
[email protected], Naval Research Laboratory, Chemistry Division,, 4555 Overlook Ave., SW, Washington, DC, 20375, United States
Get access

Abstract

Synthesis of surface passivated Zr-Al mixed metal-hydride nanoparticles was accomplished via a multi-step process. The initial reaction to produce the zirconium aluminum hydride was via decomposition of zirconium tetrahydroaluminate (Zr(AlH4)4) while exposed to ultrasound produced by a benchtop ultrasonic bath. The particles were surface passivated using carbohydrates and were shown to be stable in air and partially stable in water. TEM imaging suggests the existence of smaller particles made of a Zr-Al alloy that range in size from 1.8 nm to 7.9 nm in diameter and are interspersed with larger particles that range from tens to hundreds of nanometers in diameter. It was also shown that the carbohydrate-derived coating of the nanoparticles is present as an aluminum alkoxide gel surrounding the core particles.

Keywords

passivationZrAl
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1056: Symposium HH – Nanophase and Nanocomposite Materials V , 2007 , 1056-HH03-16
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Berube, V.; Radtke, G.; Dresselhaus, M.; Chen, G.; J. Energy Res. 31, 637 (2007)Google Scholar
2. Clark, N.J.; Wu, E.; J. Less Common Met., 166, 7 (1990)Google Scholar
3. Saita, Itoko; Toshima, Takeshi; Tanda, Satoshi; Akiyama, Tomohiro. Materials Transactions, 47(3), 931 (2006); Dehouche, Z.; Grimard, N., New Nanotechnology Research 1-67 (2006); Ni, Meng; Energy Exploration & Exploitation, 24(3), 197 (2006);Google Scholar
4. Weidenthaler, C; Pommerin, A.; Felderhoff, M.; Bogdanovic, B; Schuth, F.; Phys. Chem. Chem. Phys, 5, 5149 (2003); Marashdeh, A.; Olsen, R. A.; Lovvik, O. M.; Kroes, G.; J. Phys. Chem. C, 111, 8206 (2007);Google Scholar
5. Qingmin, Cheng; Anit, Giri; Srikanth, Raghunathan. International Patent No. 2006089222 (August 24, 2006); Kawai, Yasuaki; Haga, Tetsuya; Kojima, Yoshitsugu, Japanese Patent No. 2006152376 (June 15, 2006); Botta Filho, Walter Jose; Yavari, Alain Reza; Ribeiro de Castro, Jose Fernando; Ishikawa, Tomaz Toshimi, Brazilian Patent No. 2003005917 (August30, 2005); Kitagawa, Hiroshi; Yamauchi, Miho; Ikeda, Ryuichi; Isobe, Yuko, Japanese Patent No. 2004027346 (January 29, 2004); Kernizan, Carl F.; Spence, James R. (The Timken Company, USA). US Patent No. 6613721 (September 2, 2003);Google Scholar
6. Reird, Jr., W. E., ; Bish, J. M.; Brenner, A.; J. Electrochem. Soc. 104(1), 21 (1957);Google Scholar