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Surface Oxygen Exchange Kinetics and Oxygen Diffusion Rates in Ysz Single Crystals

Published online by Cambridge University Press:  15 February 2011

N.I. Joos ,
P.A.W. van der Heide ,
J.R. Liu ,
R. Christoffersen ,
W.K. Chu  and
C.A. Mims
N.I. Joos
Affiliation:
Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, M5S 3E5, Canada
P.A.W. van der Heide
Affiliation:
Texas Center for Superconductivity and Materials Research Science and Engineering Center. University of Houston, Houston, Texas, 77204, USA
J.R. Liu
Affiliation:
Texas Center for Superconductivity and Materials Research Science and Engineering Center. University of Houston, Houston, Texas, 77204, USA
R. Christoffersen
Affiliation:
Texas Center for Superconductivity and Materials Research Science and Engineering Center. University of Houston, Houston, Texas, 77204, USA
W.K. Chu
Affiliation:
Texas Center for Superconductivity and Materials Research Science and Engineering Center. University of Houston, Houston, Texas, 77204, USA
C.A. Mims
Affiliation:
Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, M5S 3E5, Canada, [email protected]
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Abstract

Isotope exchange with C18O2 followed by depth profiling analysis was used to study surface exchange and bulk diffusion of oxygen in single crystal ((100) surface orientation) yttria-stabilized zirconia (YSZ) in the temperature range 250°C - 350°C. The depth profiles, which were obtained using 18O(ρ,α)15N nuclear reaction analysis (NRA) and secondary ion mass spectrometry (SIMS), reveal both the bulk oxygen diffusion coefficients (D) and surface exchange coefficients (k). Bulk oxygen diffusion coefficients are consistent with an extrapolation to lower temperature of previously published results with an activation energy of 114 kJ/mol (1.2 eV). The surface exchange rates, however, depend strongly on the gas exchange species. Much higher exchange rates are observed with C18O2 than with 18O2 (over four orders of magnitude when compared to an extrapolation to lower temperatures of previously published results) with a measured activation energy of 152 kJ/mol (1.6 eV). This faster surface exchange rate enabled measurable 18O tracer profiles to be generated at lower temperatures than previously reported, further contributing to the understanding of YSZ material properties and bringing to light a possible order/disorder transition similar to that previously observed at 650°C.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 605
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. DeSouza, R.A. and Kilner, J.A., Solid State Ionics 106, 175 (1998).Google Scholar
2. Kilner, J.A. and Steele, B.C.H., Solid State Ionics 12, 89 (1984).Google Scholar
3. Manning, P.S., Sirman, J.D., and Kilner, J.A., Solid State Ionics 93, 125 (1996).Google Scholar
4. Killoran, D.R., Journal Of The Electrochemical Society 190, 172 (1962).Google Scholar
5. Manning, P.S., Sirman, J.D., DeSouza, R.A., and Kilner, J.A., Solid State Ionics 100, 1 (1997).Google Scholar
6. Steele, B.C.H., Kilner, J.A., Dennis, P.F., and McHale, A.E., Solid State Ionics 18 &19, 1038 (1986).Google Scholar
7. Liu, J.R., Li, Y.P., Chen, Q.Y., Cui, X.T., Christoffersen, R., Jacobson, A., and Chu, W.K., Nuclear Instruments & Methods In Physics Research Section B- Beam Interactions With Materials And Atoms 138, 1306 (1998).Google Scholar
8. Crank, J.. The mathematics of diffusion (Oxford University Press, Oxford, 1975).Google Scholar
9. Original reference: Solmon, H., PhD thesis, Université Paris, 1992. Data taken from [5].Google Scholar
10. Gibson, I.R. and Irvine, J.T.S., Journal Of Materials Chemistry 5, 895 (1996).Google Scholar
11. Boukamp, B.A., Hassel, B.A. van, Vinke, I.C., Vries, K.J. de, and Burgraaf, A.J., Electrochimica Acta 38, 1817 (1993).Google Scholar
12. Deportes, C., Duclot, M., Fabry, P., Fouletier, J., Hammou, A., Kleitz, M., Siebert, E., and Souquet, J.L., Electrochimie des solides (Presses Universitaires de Grenoble, 1994).Google Scholar
13. Mims, C.A., Hall, R.B., Jacobson, A.J., Lewandowski, J.T., and Myers, G., in Surface science of catalysis, In situ probes and reaction kinetics, edited by Dwyer, D.J. and Hoffmann, F.M. (American Chemical Society, Washington, 1992), pp. 230–249.Google Scholar