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Study of Thermodynamic Phase Stability of Intermetallic Thin Films of Pt2Ga, Ptga and PtGa2 on Gallium Arsenide

Published online by Cambridge University Press:  25 February 2011

Young K. Kim
Affiliation:
Department of Chemistry and Biochemistry and Solid State Science Center, University of California, Los Angeles, California 90024-1569
David K. Shuh
Affiliation:
Department of Chemistry and Biochemistry and Solid State Science Center, University of California, Los Angeles, California 90024-1569
R. Stanley Williams
Affiliation:
Department of Chemistry and Biochemistry and Solid State Science Center, University of California, Los Angeles, California 90024-1569
Larry P. Sadwick
Affiliation:
Department of Electrical Engineering Device Research Laboratory, University of California, Los Angeles, California 90024
Kang L. Wang
Affiliation:
Department of Electrical Engineering Device Research Laboratory, University of California, Los Angeles, California 90024
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Abstract

Epitaxial thin films of three different Pt-Ga intermetallic compounds have been grown on GaAs by molecular beam epitaxy (MBE). The resultant films have been annealed at various temperatures and then examined using X-ray two-theta diffraction. Both PtGa2 and PtGa thin films are chemically stable on GaAs under 1 atmosphere of N2 up to 450°C and 600°C, respectively. Thin films of Pt2Ga react with GaAs at temperatures as low as 200°C to form phases with higher Ga concentration.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

1. Brillson, L. J., J. Phys. Chem. Solids 44, 703 (1983).CrossRefGoogle Scholar
2. Sinha, A. K. and Poate, J. M., in Thin Films-Interdiffusion and Reactions, edited by Poate, J. M., Tu, K. N. and Mayor, J. W. (Interscience, New York, 1978), chap. 11.Google Scholar
3. Brillson, L. J., Surf. Sci. Rep. 2, 123 (1982).CrossRefGoogle Scholar
4. Tsai, C. T. and Williams, R. S., unpublished.Google Scholar
5. Kim, S., Hsu, L. and Williams, R. S., Phys. Rev. B 36, 3099, (1987).Google Scholar
6.JCPDS, Powder Diffraction File: Inorganic Phases (1987). International Center for Diffraction Data.Google Scholar
7. Hellner, E. and Laves, F., Z. Naturforsch., 2a, 1947, 177183.Google Scholar
8. Kim, Young K., Shuh, David K., Williams, R. S., Sadwick, Larry P. and Wang, Kang L., unpublished.Google Scholar