Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-25T15:31:10.475Z Has data issue: false hasContentIssue false
  • English
  • Français

Study of Oxetane Toughened Cationic UV Curable Marine Fouling Release Coating

Published online by Cambridge University Press:  15 March 2011

Zhigang Chen ,
Rachel Wagner ,
Sandeep Patel ,
Jongsoo Kim ,
Shane Stafslien ,
Justin Daniels ,
Lyndsi Vander Wal ,
Chavanin Siripirom  and
Bret Chisholm
Zhigang Chen
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Rachel Wagner
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Sandeep Patel
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Jongsoo Kim
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Shane Stafslien
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Justin Daniels
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Lyndsi Vander Wal
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Chavanin Siripirom
Affiliation:
Department of Coatings and Polymeric Materials, North Dakota State University, 1735 Research Park Drive, Fargo, ND, 58105
Bret Chisholm
Affiliation:
Center for Nanoscale Science and Engineering, North Dakota State University, 1805 NDSU Research Park Drive, Fargo, ND, 58102
Get access

Abstract

To develop a cationic UV curable, tough fouling-release coating for marine vessels, a difunctional oxetane monomer was used to copolymerize with the epoxy-siloxane oligomer at loading levels from 10% to 40% wt.. The resulting coatings showed enhanced solvent resistance, impact resistance and modulus, while remained hydrophobic before and after immersion in artificial sea water. In marine microorganism bioassay, these oxetane toughened coatings showed no leachate toxicity and the coating surfaces were non-toxic to biofilm growth. The fouling removal performance for these coatings was found to be microorganism dependent. Live barnacle reattachment assay showed that the toughened coatings had a removal force comparable to the reference silicone coatings Dow Corning T2 and 3140.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1005: Symposium Q – Advances In Photo-Initiated Polymer Processes and Materials , 2007 , 1005-Q02-08
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Diego, M. Y., Kiil, S., Kim, D. J., Progress in Organic Coatings, 50, 75–104 (2004).Google Scholar
2. Iwao, O., Chem.Rev., 103, 3431–3448 (2003).Google Scholar
3. Anderson, C., Atlar, M., Callow, M., Candries, M., Milne, A., Townsin, R.L., Proceeding of the Institute of Marine Engineering, Science and Technology (IMarEST) Part B: Journal of Marine Design and Operations, 4, 11–23 (2003).Google Scholar
4. Chen, Z., Webster, D. C., Polymer, 47, 3715–3726 (2006).Google Scholar
5. Chen, Z., Webster, D. C., Journal of Polymer Science, Part A: Polymer Chemistry, 44, 4435–4449 (2006).Google Scholar
6. Stafslien, S., Bahr, J., Daniels, J. A., Wal, J. W. Vander, Nevins, L., Smith, J., Schiele, K., Chisholm, B., Rev. Sci. Instr. (2006), In press.Google Scholar
7. Stafslien, S., Daniels, J. A., Chisholm, B., Christianson, D., Biofouling 23(2007).Google Scholar
8. Ekin, A., Webster, D. C., Daniels, J. W., Stafslien, S. J., Casse, F., Callow, J. A., Callow, M. E., J. Coatings Technol (2007), In press.Google Scholar
9. Stafslien, S., Bahr, J., Feser, J. M., Weisz, J. C., Chisholm, B., Ready, T. E., Boudjouk, P., J. Comb. Chem., 8, 156–162 (2006).Google Scholar
10. Casse, F., Stafslien, S., Bahr, J., Daniels, J., Finlay, J., Callow, J., Callow, M., Biofouling, 23, (2007).Google Scholar
11. Sasaki, H., Technical Conference Porceedings - RadTech 2002: The Premier UV/EB Conference & Exhibition, 64–78 (2002).Google Scholar
12. Krishnan, S., Christopher, N. W., Ober, K., Finlay, J. A., Callow, M. E., Callow, J. A., Hexemer, A., Sohn, K. E., Kramer, E. J., Fischer, D. A., Biomacromolecules, 7, 1449–1462 (2006).Google Scholar
13. Mirabedini, S. M., Pazoki, S., Esfandeh, M., Mohseni, M., Akbari, Z., Progress in Organic Coatings, 57, 421–429 (2006).Google Scholar
14. Stein, J., Christina, K. T., Wood, Darkangelo., Takemori, Michael., Vallance, Machael., Swain, Geoffrey., Kavanagh, Christopher., Kovach, Brett., Schultz, Michael., Wiebe, Deborah., Holm, Eric., Montemarano, Jean., Wendt, Dean., Smith, Celia., Meyer, Anee.. Biofouling 2003, 19, 87–94.Google Scholar
15. Stein, Judith., Truby, K., Wood, C. D., Stein, J., Gardner, M., Swain, G., Kavanagh, C., Kovach, B., Schultz, M., Wiebe, D., Holm, E., Montemarano, J., Wendt, D., Smith, C., Meyer, A.. Biofouling, 19, 71–82 (2003).Google Scholar
16. Statz, A., Finlay, J.., Dalsin, J., Callow, M., Callow, J., Messersmith, P. B., Biofouling, 22, 391–399 (2006).Google Scholar
17. Holland, R., Dugdale, T. M.., Wetherbee, R., Brennan, A. B., Finlay, J. A., Callow, J. A., Callow, M. E., Biofouling, 20, 323–329 (2004).Google Scholar
18. Chaudhury, M., Finlay, J. A., Chung, J. Y., Callow, M. E., Callow, J. A., Biofouling, 21, 41–48. (2005).Google Scholar
19. Jan, G.., Kirill, E., Biofouling, 22, 339–360 (2006).Google Scholar
20. Kavanagh, C. J., Swain, G. W., Kovach, B. S., Stein, J., Wood, C. D., Truby, K., Holm, E., Montemarano, J., Meyer, A., D. Wiebe. Biofouling, 19, 381–390 (2003).Google Scholar
21. Wendt, D. E., Kowalke, G. L., Kim, J., Singer, I. L., Biofouling, 22, 1–9 (2006).Google Scholar