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Studies on Organoaluminum Precursors OP Aluminum Nitride Fibers

Published online by Cambridge University Press:  25 February 2011

R. Thomas Baker ,
John D. Bolt ,
Gade S. Rbddy ,
D. Christopher Roe ,
Ralph H. Staley ,
Pred N. Tebbe  and
Alexander J. Vega
R. Thomas Baker
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
John D. Bolt
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
Gade S. Rbddy
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
D. Christopher Roe
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
Ralph H. Staley
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
Pred N. Tebbe
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
Alexander J. Vega
Affiliation:
E. I. du Pont de Neaours and Company, Central Research and Development Department, Experimental Station, Wilmington, DE 16868.
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Abstract

A melt-spinnable precursor of aluminum nitride fibers derived from triethylaluminum and ammonia contains AlNH, AlNH2 groups, and a small number of AlN units characteristic of aluminum nitride. The molecular weight of a spinnable composition is 070, corresponding to an average molecular weight of 13 organoaluminum groups. Ammonia, a curing agent for the fibers, accelerates elimination of ethane from the material, and decreases its solubility in toluene.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 121: Symposium H – Better Ceramics Through Chemistry III , 1988 , 471
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

Ohuchi, F. S. and Russell, P. E., J. Vac. Sci. Technol. A 5 (4), 1630(1987).Google Scholar
2. Interrante, L. V., Carpenter, L. E. II, Whitmarsh, C., and Lee, W. in Better Ceramics Through Chemistry II, edited by Brinker, C. J., Clark, D. E., and Ulrich, D. E. (Mater. Res. Soc. Proc. 73, Palo Alto, CA 1986) pp. 359–366.Google Scholar
3. Button, D. P., Yost, B. A., French, R. H., Hsu, W. Y., Bolt, J. D., Subramanian, M. A., presented at the October 19, 1987 Am. Ceram. Soc. Heeting, Electronics Div., Denver, CO, to be published in Advances in Ceramics, edited by O'Bryan, H. M., Niwa, K., Young, W., and Yan, M. F..Google Scholar
4. Tebbe, F. N., Bolt, J. D. Young, R. J. Jr, Van Buskirk, O. R., Mahler, W., Reddy, G. S., and Chowdhry, U., presented at the October 19, 1987 Am. Ceram. Soc. Meeting, Electronics Div., Denver, CO, 1987, to be published in Advances in Ceramics, edited by O'Bryan, H. M., Niwa, K., Young, W., and Yan, M. F..Google Scholar
5. Bolt, J. D. and Tebbe, F. N., presented at the October 19, 1987 Am. Ceram. Soc. Meeting, Electronics Div., Denver, CO, 1987, to be published in Advances in Ceramics, edited by O'Bryan, H. M., Niwa, K., Young, W., and Yan, M. F..Google Scholar
6. Bolt, J. D. and Tebbe, F. N., presented at the 1987 MRS Fall Meeting, Boston, MA 1987 (to be published).Google Scholar
7. Cohen, M., Gilbert, J. K., and Smith, J. D., J. Chem. Soc, 1092 (1965).Google Scholar
8. Eisch, J. J. in Organometallic Synthesis, Vol. 2, edited by Eisch, J. J. and King, R. B. (Academic Press, New York, 1981) p. 81.Google Scholar
9. Janik, J. F., Duesler, E. N., and Paine, R. T., Inorg. Chem. 26, 4241 (1987).Google Scholar
10. Corbin, D. R., Burgess, B. F., Vega, A. J., and Farlee, R. D., Anal. Chem. 59, 2722 (1987).Google Scholar
11. Aeirkhalili, S., Hitchcock, P. B., and Smith, J. D., J. Chem. Soc, Dalton, 1206 (1979).Google Scholar
12. Perego, G., Del Piero, G., Cesari, M., Zazzetta, A., and Dozzi, G., J. Organomet. Chem. 87, 53 (1975).Google Scholar