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Studies of Liquid Metal Surfaces Using Auger Spectroscopy
Published online by Cambridge University Press: 15 February 2011
Abstract
The surface composition of liquid gallium-tin alloys has been studied in an Auger electron spectrometer (AES) as a function of bulk composition and temperature. The sessile drop samples were cleaned by argon ion bombardment sputtering of the liquid. This technique produced surfaces that were entirely free of impurities within the sensitivity of AES and remained so for many days. Tin was found to be strongly adsorbed at the liquid-vacuum interface. Surface concentrations based on Auger measurements are in reasonably good agreement with values calculated from surface tension measurements interpreted in terms of a monolayer depth distribution model for the adsorbed tin.
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