Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-27T02:23:32.830Z Has data issue: false hasContentIssue false
  • English
  • Français

Structures of New Nitrides Prepared using Solid Oxide Precursors

Published online by Cambridge University Press:  10 February 2011

Joel D. Houmes ,
David S. Bem  and
Hans-Conrad Zur Loye
Joel D. Houmes
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
David S. Bem
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
Hans-Conrad Zur Loye
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
Get access

Abstract

Several novel transition metal nitrides and oxynitrides were synthesized via ammonolysis of solid state oxide precursors at temperatures ranging from 700°C-900°C and reaction times ranging from 12 hours to 4 days. The products were characterized by powder X-ray diffraction and their structures were determined by powder X-ray Rietveld refinement. The relationships between the structures of these nitrides and oxynitrides, and their similarity to the structures of the transition metal dichalcogenides, is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 410: Symposium S – Covalent Ceramics III-Science and Technology of Non-Oxides , 1995 , 113
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

(1.) Gudat, A.; Kniep, R.; Rabenau, A.; Bronger, W. and Ruschewitz, U., J. Less-Common Met. 161, 31–36 (1990).Google Scholar
(2.) Gudat, A.; Kniep, R. and Rabenau, A., Thermochim. Acta 160, 49–56 (1990).Google Scholar
(3.) LaDuca, R.L. and Wolczanski, P.T., Inorg. Chem. 31, 1311–1313 (1992).Google Scholar
(4.) Wiley, J.B. and Kaner, R.B., Science 255, 1093–1097 (1992).Google Scholar
(5.) Zachwieja, U. and Jacobs, H., Eur. J. Solid State Inorg. Chem. 28, 1055–1062 (1991).Google Scholar
(6.) Holl, M.M.B.; Wolczanski, P.T. and Van Duyne, G.D., J. Am. Chem. Soc. 112, 7989–7994 (1990).Google Scholar
(7.) Gudat, A.; Milius, W.; Haag, S.; Kniep, R. and Rabenau, A., J. Less- Common Met. 168, 305–312 (1991).Google Scholar
(8.) Gudat, A.; Kniep, R. and Rabenau, A., Angew. Chem. 103, 217–218 (1991).Google Scholar
(9.) Höhn, P. and Kniep, R., Z. Naturforsch. 47, 477–481 (1992).Google Scholar
(10.) Höhn, P.; Haag, S.; Milius, W. and Kniep, R., Angew. Chem. 103, 874–875 (1991).Google Scholar
(11.) Gudat, A. and Kniep, R., J. Alloys Compd. 179, 333–338 (1992).Google Scholar
(12.) Bem, D.S.; Gibson, C.P. and Loye, H.-C. zur, Chem. Mater. 5, 397–399 (1993).Google Scholar
(13.) Bern, D.S. and Loye, H.-C. zur, J. Solid State Chem. 104, 467 (1993).Google Scholar
(14.) Houmes, J.; Bem, D. and Loye, H. zur, Mat. Res. Soc. Symp. Proc. Vol.327 153–64 (1994).Google Scholar
(15.) Bem, D.S.; Olsen, H.P. and Loye, H.C. zur, Chem. Mater. 7, 1824–1828 (1995).Google Scholar
(16.) Elder, S.H.; DiSalvo, F.J. and Doerrer, L.H., Chem. Mater. 4, 928–937 (1992).Google Scholar
(17.) Herle, P. Subramanya; Hegde, M.S.; Vasanthacharya, N.Y.; Gopalakrishnan, J. and Subbanna, G.N., J. Solid State Chem. 112, 208–10 (1994).Google Scholar
(18.) Bem, D.S.; Lampe-Önnerud, C.M.; Olsen, H.P. and Loye, H.-C. zur, Inorganic Chemistry In Press (1996).Google Scholar
(19.) Marchand, R.; Laurent, Y.; Guyader, J.; L'Haridon, P. and Verdier, P., J. Eur. Ceram. Soc. 8, 197–213 (1991).Google Scholar
(20.) Marchand, R.; Antoine, P. and Laurent, Y., J. Solid State Chem. 107, 34–8 (1993).Google Scholar
(21.) Pors, F.; Marchand, R. and Laurent, Y., J. Solid State Chem. 107, 39–42 (1993).Google Scholar
(22.) Bacher, P.; Antoine, P.; Marchand, R.; L'Haridon, P.; Laurent, Y. and Roult, G., J. Solid State Chem. 77, 67–71 (1988).Google Scholar
(23.) Yu, C.C. and Oyama, S.T., J. Solid State Chem. 116, 205–207 (1995).Google Scholar
(24.) Houmes, J.D. and Loye, H.C. zur, In preparation (1995).Google Scholar
(25.) Larson, A.C. and Dreele, R.B. von. in “GSAS:,” (Los Alamos National Laboratory, Los Alamos, NM, 1990) p.Google Scholar
(26.) Meyer, G. and Hoppe, R., J. Less-Common Met. 46, 55 (1976).Google Scholar
(27.) Pöttgen, R.; Witte, A.M.; Jeitschko, W. and Ebel, T., J. Solid State Chem. 119, 324–330 (1995).Google Scholar