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Structure-Electronic Properties Relationships in Conducting Polymers: CP-MAS NMR and MM Analysis

Published online by Cambridge University Press:  10 February 2011

S. Bradamante ,
A. Berlin ,
A. Canavesi  and
G. Zotti
S. Bradamante
Affiliation:
Dip. di Chimica Organica e Industriale delUUniversiti e Centro CNR Sintesi e Stereochimica Speciali Sistemi Organici, via Golgi 19, 20133 Milano, Italy.
A. Berlin
Affiliation:
Dip. di Chimica Organica e Industriale delUUniversiti e Centro CNR Sintesi e Stereochimica Speciali Sistemi Organici, via Golgi 19, 20133 Milano, Italy.
A. Canavesi
Affiliation:
Dip. di Chimica Organica e Industriale delUUniversiti e Centro CNR Sintesi e Stereochimica Speciali Sistemi Organici, via Golgi 19, 20133 Milano, Italy.
G. Zotti
Affiliation:
Istituto CNR di Polarografia ed Elettrochimica Preparativa, c.so Stati Uniti 4, 35020 Padova, Italy.
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Abstract

The anodic oxidative polymerization of alkyl functionalized 4H-cyclopenta[2, 1-b:3,4-b']- dithiophene (CPDT) followed by undoping provides soluble and processable materials. We used CP MAS and high resolution NMR to analyze the monomers and polymers with the aim of correlating their structural features and conductivity. T1 relaxation values in solution and solid state were compared. Information about the preferred conformations of the polymers (backbone, distances, torsional angles) was deduced using the Molecular Modeling approach. The conclusions were derived by combining the indications obtained from both the spectroscopic and computational methods.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 413: Symposium W – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials III , 1995 , 631
Copyright
Copyright © Materials Research Society 1996

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References

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