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Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides

Published online by Cambridge University Press:  18 March 2011

H.-C. zur Loye ,
M. D. Smith ,
K. E. Stitzer ,
A. El Abed  and
J. Darriet
H.-C. zur Loye
Affiliation:
email:[email protected]
M. D. Smith
Affiliation:
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA
K. E. Stitzer
Affiliation:
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA
J. Darriet
Affiliation:
Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB-CNRS), Avenue du Dr. Schweitzer, 33608 Pessac Cedex, France
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Abstract

Single crystals of Ba8CoRh6O21 were grown out of a potassium carbonate flux. The structure was solved by a general method using the superspace group approach. The superspace group employed was R3m(00γ)0s with a = 10.0431(1) Å, c1 = 2.5946(1) Å and c2 = 4.5405(1) Å, V = 226.60(1) Å3. Ba8CoRh6O21 represents the first example of an m = 5, n = 3 member of the A3n+3mA'nB3m+nO9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting of six consecutive RhO6 octahedra followed by one distorted CoO6 trigonal prism. These chains in turn are separated from each other by [Ba]∞ chains.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG1.4
Copyright
Copyright © Materials Research Society 2001

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