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Structure and Properties of Vanadium Pentoxide Gels

Published online by Cambridge University Press:  15 February 2011

J. Livage*
Affiliation:
Spectrochimie du Solide - Université PARIS VI - 4, place Jussieu - 75230 Paris, France.
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Abstract

Transition metal oxide gels can be obtained, through a polycondensation process, by acidification of aqueous solutions. Thin layers can be easily deposited onto a substrate. Their electronic and ionic properties could lead to new developments of the sol-gel process. The semiconducting properties of V2O gels can be used for antistatic coatings or electrical switching devices. These gels exhibit a lamellar structure and can be described as particle hydrates. They are fast proton conductors and could behave as a host lattice for intercalation.

Type
Research Article
Copyright
Copyright © Materials Research Society 1984

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References

REFERENCES

1. Roy, R., J. Am. Ceram. Soc. 52, 344 (1969).CrossRefGoogle Scholar
2. Sakka, S. and Kamiya, K., J. Non-Cryst. Solids, 42, 403 (1980).CrossRefGoogle Scholar
3. Mukherjee, S.P., J. Non-Cryst. Solids, 42, 477 (1980).CrossRefGoogle Scholar
4. Partlow, D.P. and Yoldas, B.E., J.Non-Cryst. Solids,46,153 (1981).CrossRefGoogle Scholar
5. Dislich, H., J. Non-cryst. Solids, 57, 371, (1983).CrossRefGoogle Scholar
6. Dislich, H. and Hussmann, E., Thin Solid Films, 77, 129 (1981).CrossRefGoogle Scholar
7. Dislich, H. and Hinz, P., J. Non-Cryst. Solids, 48, 6 (1982).CrossRefGoogle Scholar
8. Dislich, H., Angew. Chem. Int. Ed. Engl., 10, 363 (1971).CrossRefGoogle Scholar
9. Brinker, C.J. and Mukherjee, S.P, thin Solid Films, 77, 141 (1981).CrossRefGoogle Scholar
10. Mukherjee, S.P and Lowdermilk, W.H., J. Non-Cryst. Solids, 48, 177 (1982).CrossRefGoogle Scholar
11. Nelson, R.L., Ramsay, J.D.F., Woodhead, J.L., Caiens, J.A. and Crossley, J.A.A., Thin Solid Films, 81, 329 (1981).CrossRefGoogle Scholar
12. Dislich, H., Hinz, P. and Wolf, G., US-Pat. 4 229 491 (1978).Google Scholar
13. Perthuis, H., Colomban, Ph., Boilot, J.P. and Velasco, G., Ceramic Powders, Vincenzi, P. ed. (Elsevier-Amsterdam 1983) 575.Google Scholar
14. Livage, J. and Lemerle, J., Ann. Rev. Mater. Sci., 12, 103 (1982).CrossRefGoogle Scholar
15. Livage, J., Studies in Inorganic Chemistry, Megestaar, R., Heijligers, H.J.M. and Schoonman, J. eds. (Elsevier, Amsterdam 1983) 17.Google Scholar
16. Sanchez, c., Babonneau, F., Morineau, R. and Livage, J., Phil. Mag. B, 47 279 (1983).CrossRefGoogle Scholar
17. Chemseddine, A., Morineau, R. and Livage, J., Solid State Ionics, 9–10, 357 (1983).CrossRefGoogle Scholar
18. Massart, R., Trans, I.E.E.E.. on Magnetics, 17, 1241 (1981).CrossRefGoogle Scholar
19. Dzimitrowicz, D.J., Goodenough, J.B. and Wiseman, P.J., Mat. Res. Bull., 17, 971 (1982).CrossRefGoogle Scholar
20. England, W.A., Cross, M.G., Hamnett, A., Wiseman, P.J. and Goodenough, J.B., Solid State Ionics, 1, 231 (1980).CrossRefGoogle Scholar
21. Bradley, D.C., Mehrotra, R.C. and Gaur, D.P., Metal Alkoxides, Academic Press, London, (1978).Google Scholar
22. Kiss, K., Magder, J., Vukasovich, M.S. and Lockhart, R.J., J. Am. Ceram. Soc. 49, 291 (1966).CrossRefGoogle Scholar
23. Smith, J.S., Dolloff, R.T. and Mazdiyasni, M.S., J. Am. Ceram. Soc., 53, 91 (1970).CrossRefGoogle Scholar
24. Kepert, D.L., The early transition metals, Academic Press, London (1972).Google Scholar
25. Baes, C.F. and Mesmer, R.E., the hydrolysis of cations, John Wiley, New-York, (1976).Google Scholar
26. Johansson, G., Acta Chem. Scand., 16, 403 (1962).CrossRefGoogle Scholar
27. Johansson, G., Acta Chem. Scand., 14, 771 (1960).CrossRefGoogle Scholar
28. Souchay, P., Ions minéraux condensés, Masson Ed. Paris, (1969).Google Scholar
29. Lemerle, J., Nejem, L. and Lefebvre, J., J. Chem. Res. 301 (1978).Google Scholar
30. Gharbi, N., Sanchez, C., Livage, J., Lemerle, J., Nejem, L. and Lefebvre, J., Inorg. Chem. 21, 2758 (1982).CrossRefGoogle Scholar
31. Aldebert, P., Baffier, N., Gharbi, N. and Livage, J., Mat. Res. Bull., 16, 669 (1981).CrossRefGoogle Scholar
32. Abello, L. and Pommier, C., J. Chim. Phys., 80, 373 (1983).CrossRefGoogle Scholar
33. Legendre, J.J. and Livage, J., J. Colloids and Interface Science, 94, 75 (1983).CrossRefGoogle Scholar
34. Legendre, J.J., Aldebert, P., Baffier, N. and Livage, J., J. Colloids and Interface Science, 94, 84 (1983).CrossRefGoogle Scholar
35. Sanchez, C., Livag, J. and Lucazeau, G., J. Raman Spectra, 12, 68 (1982).CrossRefGoogle Scholar
36. Vandenborre, M.T., Prost, R., Huard, E. and Livage, J., Mat. Res. Bull., 18, 1133 (1983).CrossRefGoogle Scholar
37. Abello, L., Husson, E., Repelin, Y. and Lucazeau, G., J.Mol.Str.(submitted).Google Scholar
38. Barboux, P., Baffier, N., Morineau, R. and Livage, J., Solid State Ionics, 9–10, 1973 (1983).Google Scholar
39. Howe, A.T. and Shilton, M.G., J. Solid State Chem., 34, 149 (1980).CrossRefGoogle Scholar
40. Krener, K.D., Rabenau, A. and Weppner, W., Angew. Chem. Int. Engl. Ed., 21, 208–9 (1982).Google Scholar
41. Murawski, L., Chung, C.H. and Mackenzie, J.D., J. Non-Cryst. Solids, 32, 91 (1979).CrossRefGoogle Scholar
42. Livage, J., J. Phys., 42, C4, 981 (1981).Google Scholar
43. Austin, I.G. and Mott, N. F, Adv. in Physics, 18, 41 (1969).CrossRefGoogle Scholar
44. Holstein, T., Ann. Phys., 8, 343 (1959).CrossRefGoogle Scholar
45. Schnakenberg, J., Phys. Stat. Sol.(b), 28, 623 (1968).CrossRefGoogle Scholar
46. Sanchez, C., Babonneau, F., Morineau, R., Livage, J. and Bullot, J., Phil. Mag. B, 47, 279 (1983).CrossRefGoogle Scholar
47. Bullot, J., Cordier, P., Gallais, O., Gauthier, M. and Livage, J., Phys. Stat. Sol.(a), 68, 357 (1981).CrossRefGoogle Scholar
48. Kodak Pathé, French Patents BF 2318 442 (1977) and BF 2429 252 (1979).Google Scholar
49. Bullot, J. and Livage, J., French Patent, 81, 13665 (1981).Google Scholar
50. Bullot, J., Gallais, O., Gauthier, M. and Livage, J., Phys. Stat. Sol.(a), 71, K1-5 (1982).Google Scholar
51. Schollorn, R., Angew. Chem. Int. Engl. Ed., 19, 983 (1980).CrossRefGoogle Scholar
52. Whittingham, M.S. and Dines, M.B., Survey of 'progress in chemistry, 9, 55 (1980).CrossRefGoogle Scholar
53. Aldebert, T. and Paul-Boncour, V., Mat. Res. Bull., 18, 1263 (1983).CrossRefGoogle Scholar
54. Aldebert, P., Baffier, N., Legendre, J.J. and Livag, J., Rev. Chimie Minérale, 19, 485 (1982).Google Scholar
55. Araki, B., Mailhé, C., Baffier, N., Livage, J. and Vedel, J., Solid State Ionics, 9–10, 439 (1983).CrossRefGoogle Scholar
56. Bouhaouss, A. and Aldebert, P., Mat. Res. Bull., 18, 1247 (1983).CrossRefGoogle Scholar