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Structural Problems and Non Stoichiometry in Thallium, Bismuth, and Lead Cuprates

Published online by Cambridge University Press:  21 February 2011

B. Raveau ,
C. Michel ,
M. Hervieu ,
D. Groult  and
J. Provost
B. Raveau
Affiliation:
Laboratoire de Cristallographie et Sciences des Matériaux - ISMRA-Bd du Maréchal Juin 14032- Caen cedex- France
C. Michel
Affiliation:
Laboratoire de Cristallographie et Sciences des Matériaux - ISMRA-Bd du Maréchal Juin 14032- Caen cedex- France
M. Hervieu
Affiliation:
Laboratoire de Cristallographie et Sciences des Matériaux - ISMRA-Bd du Maréchal Juin 14032- Caen cedex- France
D. Groult
Affiliation:
Laboratoire de Cristallographie et Sciences des Matériaux - ISMRA-Bd du Maréchal Juin 14032- Caen cedex- France
J. Provost
Affiliation:
Laboratoire de Cristallographie et Sciences des Matériaux - ISMRA-Bd du Maréchal Juin 14032- Caen cedex- France
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Abstract

An over view of the crystal chemistry of the layered bismuth, thallium and lead cuprates is presented here. The classification of these oxides is examined, and the problems of non stoichiometry, especially of extented defects and incommensurability of the structures, are discussed in connection with the superconducting properties of these materials. A particular attention is paid for the role of the lone pair cations in the structural properties of these oxides.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 156: Symposium M – High Temperature Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry , 1989 , 129
Copyright
Copyright © Materials Research Society 1989

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References

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