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Structural Changes in Fast Ion Conducting Chloride Doped Potassium Borate Glasses

Published online by Cambridge University Press:  21 February 2011

F.A. Fusco ,
M. Massot ,
M. Oueslati ,
E. Haro ,
H.L. Tuller  and
M. Balkanski
F.A. Fusco
Affiliation:
Massachusetts Institute of Technology, Crystal Physics & Optical Electronics Laboratory, Department of Materials Science and Engineering, Cambridge, MA
M. Massot
Affiliation:
Universite Pierre et Marie Curie, Laboratoire de Physique des Solides, Paris, France
M. Oueslati
Affiliation:
Universite Pierre et Marie Curie, Laboratoire de Physique des Solides, Paris, France
E. Haro
Affiliation:
Universite Pierre et Marie Curie, Laboratoire de Physique des Solides, Paris, France
H.L. Tuller
Affiliation:
Massachusetts Institute of Technology, Crystal Physics & Optical Electronics Laboratory, Department of Materials Science and Engineering, Cambridge, MA
M. Balkanski
Affiliation:
Universite Pierre et Marie Curie, Laboratoire de Physique des Solides, Paris, France
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Abstract

The effects of halide substitution on ionic conductivity in potassium borate glasses are different from those observed in their Li and Na analogs. Physical property and Raman spectroscopy results suggest that this behavior is associated with differences in the glass network structure induced by the presence of different interstitial alkali cations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 189
Copyright
Copyright © Materials Research Society 1989

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