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Structural and Electrochemical Investigation of Na+ Insertion Into λ-Mn1-xNixO2

Published online by Cambridge University Press:  22 June 2015

J. R. Kim  and
G. G. Amatucci
J. R. Kim
Affiliation:
Energy Storage Research Group Department of Materials Science and Engineering Rutgers, the State University of New Jersey
G. G. Amatucci
Affiliation:
Energy Storage Research Group Department of Materials Science and Engineering Rutgers, the State University of New Jersey
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Abstract

Increased demand for low cost energy storage options has expanded the scope of Na+ batteries considerably; and with the growing interest in Na-based chemistries, the importance of high voltage positive electrodes is quickly realized as the Na/Na+ redox introduces lower operating voltages as compared to Li/Li+ based electrochemical cells. The 4.7V LiMn1.5Ni0.5O4 spinel has exhibited considerable properties as a high voltage Li+ positive electrode, with a host structure (λ-Mn0.75Ni0.25O2) that may provide an analogous high voltage Na+ positive electrode. Structural and electrochemical properties of NaxMn1.56Ni0.44O4 and NaxMn2O4 are investigated for the first time[1] utilizing ex-situ, in-situ X-ray diffraction, and high-resolution electrochemical techniques to provide an insightful study of the Na+ insertion mechanism.

Keywords

energy storagex-ray diffraction (XRD)intercalation
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1810: Symposium YY – Insights for Energy Materials Using In-Situ Characterization , 2015 , mrss15-2136145
Copyright
Copyright © Materials Research Society 2015 

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