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The Stability and Reversibility of TiCl3 Doped LiBH4

Published online by Cambridge University Press:  01 February 2011

Ming Au ,
Arthur R Jurgensen ,
William A Spenser ,
Donald L Anton  and
Frederick E Pinkerton
Ming Au
Affiliation:
[email protected], Savannah River National Laboratory, Energy Security, 999-2w, Aiken, SC, 29808, United States, 8035078547
Arthur R Jurgensen
Affiliation:
[email protected], Savannah River National Laboratory, Aiken, SC, 29808, United States
William A Spenser
Affiliation:
[email protected], Savannah River National Laboratory, Aiken, SC, 29808, United States
Donald L Anton
Affiliation:
[email protected], Savannah River National Laboratory, Aiken, SC, 29808, United States
Frederick E Pinkerton
Affiliation:
[email protected], General Motor, Warren, MI, 48088, United States
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Abstract

In an effort to develop reversible metallic borohydrides with high hydrogen storage capacities and low dehydriding temperature, modifications to LiBH4 with metal halides TiCl3 have been conducted. Adding TiCl3 to LiBH4 effectively reduced the dehydriding temperature through an ion exchange interaction by producing instable transition metal borohydrides and lithium salts. The material LiBH4+0.1TiCl3 desorbed 3.5wt% and 8.5wt% hydrogen at 150°C and 450°C respectively. Subsequent re-absorption of 6wt% hydrogen at 500°C and 70 bars was observed. The XRD analysis of the rehydrided samples confirmed the partial reformation of LiBH4. However, adding more TiCl3 made material more volatile and irreversible. TGA-RGA analyses indicated diborane evolution during dehydrogenation resulting in unrecoverable capacity loss and irreversibility. TiCl3 reduced LiBH4 stability and also made material irreversible.

Keywords

energy-storagehydrogenationchemical reaction
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1042: Symposium S – Materials and Technology for Hydrogen Storage , 2007 , 1042-S05-05
Copyright
Copyright © Materials Research Society 2008

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References

[1] Muller, A., Havre, L. et al. US Patent 4193978, (1980)Google Scholar
[2] Zuttel, A., Rentsch, S. et al. J.Alloy.Compd. 356–357(2003)515–520 Google Scholar
[3] Orimo, S., Nakamori, Y. et al. “Dehydriding and rehydriding reactions of LiBH4 ”, J.Alloy.Comp. 404–406 (2005)427 Google Scholar
[4] Pinkerton, F., Meisner, G. et al. J.Phys.Chem.B 110(2005)6–8 10.1021/jp0455475Google Scholar
[5] Vajo, J., Skeith, S. et al. J.Alloy.Compd. 390(2005)55–61 Google Scholar
[6] Nakamori, Y., Li, H. et al. Materials Transactions, V47, N8(2006)1898–1901 Google Scholar
[7] Vajo, J. and Skeith, S., J.Phys.Chem.B. 109 (2005) 3719–3722 Google Scholar
[8] Au, M. and Jurgensen, A., J.Phys.Chem.B 110(2006)7062–7067 Google Scholar
[9] Au, M., Jurgensen, A. et al. J.Phys.Chem.B 110(2006)26482–26487 Google Scholar
[10] Zhang, Y., Zhong, W-S. et al. Int.J.Hydrogen.Energy. in pressdoi:10.1016/j.ijhydene.2007.04.010Google Scholar
[11] Shore, S.G. and Parry, R.W., J.Am.Chem.Soc. 80(1958)8–12 Google Scholar
[12] Schlesinger, H.I., Brown, H. et al. J.Am.Chem.Soc. 75(1953)199–204 Google Scholar
[13] Hoekstra, H. and Katz, J.J., J.Am.Chem.Soc. 71(1949)2488–2492 Google Scholar
[14] Schlesinger, H.I., Brown, H. et al. J.Am.Chem.Soc. 75(1953)209–213 Google Scholar
[15] Heisenberg, W., Bothe, W. et al. Z. Naturforsch. 1952, 7b, 58–60 Google Scholar
[16] Jeon, E. and Cho, Y-W, J.Alloy.Compd. 422(2006)1898–1901 Google Scholar
[17] Jensen, C., “Fundamental study of high capacity reversible metal hydrides”, DOE Hydrogen program annual review meeting, 5/16/2007Google Scholar
[18] Zhao, J-C., Andrus, M. et al. “Light weight intermetallics for hydrogen storage”, DOE Hydrogen program annual review meeting, 5/16/2007Google Scholar
[19] Nakamori, Y., Wima, K. et al. Phys.Rev.B. in pressGoogle Scholar
[20] Orimo, S., Nakamori, Y. et al. J.Alloy.Compd. 404–406(2005)427–430 Google Scholar
[21] Johnson, K. and Sholl, D., “First principle modeling of hydrogen storage in metal hydride systems”, DOE Hydrogen program annual review meeting, 5/16/2007Google Scholar
[22] Nakamori, Y., Li, H. et al. Materials Transactions, V47, N8(2006)1898–1901 Google Scholar
[23] Olson, G.L. and Vajo, J.J., “Thermodynamically Tuned Nanophase materials for Reversible Hydrogen Storage”, Project ID#ST16, 2006 DOE Hydrogen Program Annual Review Meeting, Washington, DC, May16-19, 2006 Google Scholar