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Published online by Cambridge University Press: 26 February 2011
The magnetoresistance of conjugated polymer poly [2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) based organic light-emitting diodes (OLED) was investigated at both forward and reverse bias at liquid nitrogen temperature. We find that the reverse bias yields a largely increased magnetoresistance when the electron-hole capture zone is away from the metal electrode as compared to the forward bias with the electron-hole capture zone close to the metal electrode. The electroluminescence suggests that the deposited metal atoms enhance the spin-orbital coupling at the polymer/metal interface and consequently lead to electron-hole capture zone-dependent magnetic field effects in organic semiconductor devices.