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Spectroscopy and Photoreactions of Organometallic Molecules on Surfaces
Published online by Cambridge University Press: 15 February 2011
Abstract
A study of the UV photochemistry of organometallic molecules in the vapor and adsorbed phases is discussed. The gas-phase spectra is interpreted on the basis of molecular orbital theory and experimental data. The absorption spectra of the surface adlayers are determined by computer subtraction of the gas-phase spectra and an intepretation is provided. The influence of metalsubstrate microstructure on UV photochemical reactions of metal alkyls is briefly discussed.
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- Research Article
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- Copyright © Materials Research Society 1983
References
REFERENCES
1.
Ehrlich, D.J., Osgood, R.M. Jr., and Deutsch, T.F., IEEE Journal of Quantum Electronics, 16
1233 (1980).CrossRefGoogle Scholar
2.
Herzberg, G., Molecular Spectra and Molecular Structure III. Electronic Spectra and Electronic Structure of Polyatomic Molecules, D. Van Nostrand, (1966).Google Scholar
5.
Kellman, M.E., Pechukas, P. and Bersohn, R., Chem. Phys. Letters, 83
304 (1981).CrossRefGoogle Scholar
7.
Rytz-Froidevaux, Y., Salathè, R.P., Gilgen, H.H. and Weber, H.P., Appl. Phys.
A27
133 (1982).CrossRefGoogle Scholar
8. See, for example, Young, D.M. and Crowell, A.D., Physical Adsorption of Gases, Butterworths, (1962).Google Scholar
10. For a preliminary account see paper Phys. 96, C.J. Chen and R.M. Osgood, Jr., 184th Annual American Chemical Society Meeting, Kansas City, MO.Google Scholar
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