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Spectroscopy and Photoreactions of Organometallic Molecules on Surfaces

Published online by Cambridge University Press:  15 February 2011

C. J. Chen
Affiliation:
Columbia Radiation Laboratory and Department of Electrical Engineering, Columbia University, New York, NY 10027
R. M. Osgood Jr.
Affiliation:
Columbia Radiation Laboratory and Department of Electrical Engineering, Columbia University, New York, NY 10027
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Abstract

A study of the UV photochemistry of organometallic molecules in the vapor and adsorbed phases is discussed. The gas-phase spectra is interpreted on the basis of molecular orbital theory and experimental data. The absorption spectra of the surface adlayers are determined by computer subtraction of the gas-phase spectra and an intepretation is provided. The influence of metalsubstrate microstructure on UV photochemical reactions of metal alkyls is briefly discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1983

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References

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