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A Solid State Multinuclear Magnetic Resonance Study of the Sol-Gel Process using Polysilicate Precursors

Published online by Cambridge University Press:  28 February 2011

W. G. Klemperer ,
V. V. Mainz  and
D. M. Millar
W. G. Klemperer
Affiliation:
School of Chemical Sciences and Materials Research Laboratory, University of Illinois, Urbana, IL 61801
V. V. Mainz
Affiliation:
School of Chemical Sciences and Materials Research Laboratory, University of Illinois, Urbana, IL 61801
D. M. Millar
Affiliation:
School of Chemical Sciences and Materials Research Laboratory, University of Illinois, Urbana, IL 61801
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Abstract

A solid state multinuclear NMR study of the sol-gel process was performed using the molecular building blocks tetramethoxysilane, hexamethoxydisiloxane, octamethoxytrisiloxane and octamethoxyoctasilsesquioxane as precursor monomers. Water content, solvent content, and hydrolysis/condensation processes were monitored using 17O, 13C, and 29Si FT, FTMAS and CPMAS NMR techniques.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 73: Symposium H – Better Ceramics Through Chemistry II , 1986 , 15
Copyright
Copyright © Materials Research Society 1986

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References

REFERENCES

1. Harris, R. K., Knight, C. T. G. and Smith, D. N., J. Chem. Soc. Chem. Comm. 726 (1980).CrossRefGoogle Scholar
2. Marsmann, H. C., Meyer, E., Vongehr, M. and Weber, E. F., Makromol. Chem. 184, 1817 (1983).CrossRefGoogle Scholar
3. Artaki, I., Bradley, M., Zerda, T. W., and Jonas, J., J. Phys. Chem. 89, 4399 (1985).CrossRefGoogle Scholar
4. Orcel, G. and Hench, L., J. Noncryst. Solids 79, 177 (1986)CrossRefGoogle Scholar
5. Klemperer, W. G., Mainz, V. V., and Millar, D. M., this volume.Google Scholar
6. Assink, R. A. and Kay, B. D., in Better Ceramics Through Chemistry, edited by Brinker, C. J., Ulrich, D. R., and Clark, D. E. (Elsevier Science Publishers, New York, 1984), p. 301.Google Scholar
7. Fyfe, C. A., Solid State NMR for Chemists (C.F.C. Press, Ontario, 1983).Google Scholar
8. Tricot, Y. and Niederberger, W., Biophys. Chem. 9, 195 (1979).CrossRefGoogle Scholar
9. Maciel, G. E., Haw, J. F., Chuang, I.-S., Hawkins, B. L., Early, T. A., McKay, D. R. and Petrakis, Leon, J. Am. Chem. Soc. 105, 5529 (1983).CrossRefGoogle Scholar
10. Maciel, G. E. and Sindorf, D. W., J. Am. Chem. Soc. 102, 7606 (1980).CrossRefGoogle Scholar
11. Lippmaa, E. T., Samosan, A. V., Brei, V. V. and Gorlov, Y. I., Dokl. Akad. Nauk SSSR 259, 403 (1981).Google Scholar
12. 17O NMR: see reference 8; 13C NHR: see reference 7, pp. 324–329; 29Si NMR: Levy, G. C., Cargioli, J. D., Juliano, P. C. and Mitchell, T. D., J. Am. Chem. Soc. 95, 3445 (1973).CrossRefGoogle Scholar
13. a) Smith, J. V. and Blackwell, C. S., Nature 303, 223 (1983); b) E. Dupree and R. F. Pettifer, Nature 308, 523 (1984).CrossRefGoogle Scholar