Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-25T15:37:45.737Z Has data issue: false hasContentIssue false

Solid Solution Hardening of Intermetallic Compounds

Published online by Cambridge University Press:  01 January 1992

Robert L. Fleischer*
Affiliation:
Rensselaer Polytechnic Institute, Troy, NY 12180-3590 (formerly General Electric Research & Development Center, Schenectady, NY 12301)
Get access

Abstract

Solid solution hardening is sought and observed in two B2(cP2) CsCl and two C15(cF24) Cu2Mg type structures. New data are presented for the high-temperature compounds AlCo, AlRu, and Cr2Zr; prior data of Livingston on Cu2Mg are analyzed. From lattice parameters and specific gravities, cell occupancy numbers have been measured and used to infer likely defect types and concentrations. The effects of constitutional defects in binary compounds correlate with traditional substitutional solution hardening from elastic interactions due to size differences and modulus differences. The hardening from ternary solutes is similar in magnitude, but the defect structures are complicated and not yet adequately understood.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wood, D.L and Westbrook, J.H., Trans, AIME 224,1024 (1992).Google Scholar
2. Mishima, Y., Ochiai, S., Hamao, H., Yodogawa, M., and Suzuki, T., Japan. Inst. Met. 27, 648 (1986).Google Scholar
3. Livingston, J.D., Hall, E.L., and Koch, E.F., MRS Conf. Proc. 133, 243 (1989).Google Scholar
4. Livingston, J.D., “Deformation and Defects in Laves-Phase Intermetallic Compounds,” Gen. Elect. Report 88CRD001 to the U.S. Dept. of Energy, Grant DE-FG02-87ER45296.A00(1987)Google Scholar
5. Fleischer, R.L., J. Mat. Res., 7 (Jan. 1993).Google Scholar
6. Fleischer, R.L., Acta Met. Mat., 41 (1993).Google Scholar
7. Fleischer, R.L., Scripta Met. Mat. 27, 799 (1992).Google Scholar
8. Mott, N.F. and Nabarro, F.R.N., Proc. Phys. Soc. 52, 86 (1940).Google Scholar
9. Crussard, C., Metaux and Corrosion 25, 203 (1950).Google Scholar
10. Fleischer, R.L., Acta Met. 11, 203 (1963).Google Scholar
11. Chang, Y.A. and Neumann, J.P., Prog. Solid State Chem. 14, 221 (1982).Google Scholar
12. Westbrook, J.H., J. Electrochem. Soc. 104, 369 (1957).Google Scholar
13. Fleischer, R.L., Chapter 3, pp. 93162 in The Strengthening of Metals, Peckner, D., ed., Reinhold Press, New York (1964).Google Scholar