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Solid Propellant Flame Structure

Published online by Cambridge University Press:  10 February 2011

T. P. Parr  and
D. M. Hanson-Parr
T. P. Parr
Affiliation:
Combustion Diagnostics Laboratory, Research Division, Code 474320D, Naval Air Warfare Center, China Lake, CA 93555–6001, (619) 939-3367 939-6569 (FAX), [email protected]
D. M. Hanson-Parr
Affiliation:
Combustion Diagnostics Laboratory, Research Division, Code 474320D, Naval Air Warfare Center, China Lake, CA 93555–6001, (619) 939-3367 939-6569 (FAX), [email protected]
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Abstract

Planar Laser Induced Fluorescence (PLIF), UV/Vis Absorption, and thermocouple measurements were done for HNF, RDX, HMX, and XM39 deflagration with and without CO2 laser-support. RDX and especially HNF have very short self-deflagration flame length scales. HMX and XM39 have taller self-deflagration flames. XM39 has a marked dark zone with plateau temperature about 1400K. RDX's dark zone, present under laser supported deflagration, collapses when the external laser flux is removed. PLIF was used to measure the 2D NH, OH, and CN species profiles for these materials and OH temperature profile for RDX and HNF under non-laser supported conditions. The best spatial resolution for the RDX PLIF was about 4μm. Sandwiches of HNF and various binders were studied with PLIF and while obvious diffusion flames were present at low pressure, they are weak and are not expected to be burn rate controlling.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 418: Symposium GG – Decomposition, Combustion, and Detonation Chemistry of Energetic Materials , 1995 , 207
Copyright
Copyright © Materials Research Society 1996

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References

1. “RDX Laser Assisted Flame Structure”, Hanson-Parr, Donna and Parr, Tim, Proceedings of the 31Ist JANNAF Combustion Subcommittee Meeting, Vol. II, page 407 (1994), CPIA publication 620.Google Scholar
2. “Solid Propellant Flame Structure”, Parr, Tim and Hanson-Parr, Donna, in Non-Intrusive Combustion Diagnostics, Kuo, Kenneth K. and Parr, Tim editors, Begell House, Inc. New York (1994), pp. 571–599.Google Scholar
3. “A Study of the Gas-Phase Processes of RDX Combustion Using a Triple Quadrupole Mass Spectrometer”, Lee, Y.J., Tang, C.J., and Litzinger, T.A., Proceedings of the 31st JANNAF Combustion Subcommittee Meeting, Vol.1I, page 425–430 (1994), CPIA publication 620.Google Scholar
4. “Chemical Structure of the Gas Phase above Deflagrating RDX: Comparison of Experimental Measurements and Model Predictions”, Fetherolf, B.L., and Litzinger, T.A., Proceedings of the 30h JANNAF Combustion Committee Meeting, CPIA pub. 606, Vol. II, p 15, (1993).Google Scholar
5. “Dynamic Flame Probe Mass Spectrometry and Condensed-System Decomposition ”, Korobeinichev, O.P., Comb. Expi. and Shock Waves 23 565–576 March 1988.Google Scholar
6. “Processes in Hexogen Flames”, Ermolin, N.E., Korobeinichev, O.P., Kuibida, L.V. and Fomin, V.M., Comb. Expl. and Shock Waves 24 400–407 Jan. 1989.Google Scholar
7. “CARS Probe of RDX Decomposition”, Aron, Kenneth and Harris, L.E., Chem. Phys. Lett. 103(5), 413–417 (1983).Google Scholar
8. “CARS Diagnostics of Solid Propellant Combustion at Elevated Pressures”, Stufflebeam, John H. and Eckbreth, Alan C., Combust. Sci. Tech. 66 163–179 (1989).Google Scholar
9. “Infrared multiphoton dissociation of RDX in a molecular beam”, Zhao, X., Hintsa, E., and Lee, Y.T., J. Chem. Phys. 88(2), 801–810 (1988)Google Scholar
10. “Spectral Studies of Solid Propellant Combustion IV. Absorption and Burn Rate Results for M43, XM39, and M 10 Propellants”, Teague, M. Warfield, Singh, Gurbax, and Vanderhoff, John A., Technical Report ARL-TR-180 August 1993.Google Scholar
11. “Multichannel Infrared Absorption Spectroscopy Applied to Solid Propellant Flames”, Modiano, S.H. and Vanderhoff, J.A., Proceedings of the 30th JANNAF Combustion Subcommittee Meeting, Hyatt Regency Hotel and NPGS Monterey, CA 15–19 November 1993, Vol. II, p.227.Google Scholar
12. “Improvements in Infrared Absorption of Solid Propellant Flames”, Modiano, S.H. and Vanderhoff, J.A., Proceedings of the 31st JANNAF Combustion Subcommittee Meeting, Vol. II, page 325–332 (1994), CPIA publication 620.Google Scholar
13. “A Comparison of the Physical and Chemical Processes Governing the CO2 Laser-Induced Pyrolysis and Deflagration of XM39 and M43”, Fetherolf, B.L., Litzinger, T.A., Lu, Y-C. and Kuo, K.K., Proceedings of the 30th JANNAF Combustion Subcommittee Meeting, Vol. II, page 183–193 (1993), CPIA publication 606.Google Scholar
14. “A Study of Gas-Phase Processes During the Deflagration of RDX Composite Propellants Using a Triple Quadrupole Mass Spectrometer”, Litzinger, T.A., Lee, Y.J., and Tang, C.J., Proceedings of the 31st JANNAF Combustion Subcommittee Meeting, Vol. II, page 307–316 (1994), CPIA publication 620.Google Scholar
15. Many various E-Mail private communications.Google Scholar
16. “Scanning Calorimetric Determination of Vapor-Phase Kinetics Data”, Rogers, R.N. and Daub, G.W., Analy. Chem. 45, pp.596–600 (1973).Google Scholar
17. Summary workshop report of the Kinetic and Related Aspects of Propellant Combustion Chemistry Panel, held at the 31st JANNAF Combustion Subcommittee Meeting, presented at the 32nd JANNAF Combustion Subcommittee Meeting, Huntsville, AL, Oct. 1995.Google Scholar
18. “Advanced Oxidizers Diffusion Flame Structure”, Parr, Tim and Hanson-Parr, Donna, Proceedings of the 31st JANNAF Combustion Subcommittee Meeting Vol. II, p. 333–344 (1994) CPIA publication 620.Google Scholar
19. “Advanced Diagnostic Techniques for NonSteady Burning of Solid Propellants”, Parr, T.P. and Hanson-Parr, D.M. in Progress in Astronautics and Aeronautics, edited by L. De Luca, E.W. Price, and M. Summerfield, Volume 143, pp. 261–324, (1992).Google Scholar
20. “Nitramine Flame Structure as a Function of Pressure”, Parr, T.P. and Hanson-Parr, D.M., Proceedings of the 26th JANNAF Combustion Committee Meeting, CPIA pub. 529, Vol. I, p 27, (1989).Google Scholar
21. “Temperature and Species Profiles in Propellant Ignition and Combustion”, Parr, T.P. and Hanson-Parr, D.M., Proceedings of the 24th JANNAF Combustion Committee Meeting Vol. I, p 367 (1987) CPIA publication 476.Google Scholar
22. “The Application of Imaging Laser Induced Fluorescence to the Measurement of HMX and Aluminized Propellant Ignition and Deflagration Flame Structure”, Parr, T.P. and Hanson-Parr, D.M., Proceedings of the 23rd JANNAF Combustion Committee Meeting Vol. I, p 249 (1986) CPIA publication 457.Google Scholar
23. “Rapidly Sequenced Pairs of Two-Dimensional Images of OH Laser Induced Fluorescence in a Flame”, Dyer, M.J. and Crosley, D.R., Optics Letters 9, 217 (1984).Google Scholar
24. “An Eigenvalue Approach for Computing the Burning Rate of RDX Propellants”, Prasad, K. and Smooke, M., presented at the 32nd JANNAF Combustion Subcommittee Meeting, Huntsville, AL, Oct. 1995.Google Scholar
25. “Laboratory Ignition and Combustion Data and the Determination of Global Kinetics and Energetic Parameters of RDX”, Atwood, A.I., Curran, P.O. and, and Price, C.F., presented at the 32nd JANNAF Combustion Subcommittee Meeting, Huntsville, AL, Oct. 1995.Google Scholar
26. “Further Improvements to FTIR Absorption Spectroscopy of Propellant Flames for Profiling of Species and Temperature”, Mallery, C.F. and Tynell, S.T., presented at the 32nd JANNAF Combustion Subcommittee Meeting, Huntsville, AL, Oct. 1995.Google Scholar
27. “Combustion of Ammonium Perchlorate - Polymer Sandwiches”, Price, E.W. et. al., Comb. Flame 63, 381 (1986).Google Scholar
28. “Dependence of Burning Rate of AP-Polymer Sandwiches on Thickness of Binder Price and Sambamurthi, J.K., Proceedings of the 20th JANNAF Combustion Subncommittee Meeting,. (1983) CPIA Publication 383.Google Scholar
29. “Effect of Types of Binder and Burning Rate Catalysts on Edge Burning AP-binder-AP Sandwiches”, Price, E.W., Markou, C., and Sigman, R.K., Proceedings of the 26th JANNAF Combustion Subcommittee Meeting, Vol. II, p 93 (1989), CPIA Publication 529.Google Scholar
30. “Role of the Leading Edge of the Diffusion Flame in Combustion of Solid Propellants”, Price, E.W. et. al., Proceedings of the 27th JANNAF Combustion Subcommittee Meeting, Vol. III, p. 31 (1990), CPIA publication 557.Google Scholar
31. “Propellant Diffusion Flame Structure”, Parr, Tim and Hanson-Parr, Donna, Proceedings of the 28th JANNAF Combustion Subcommittee Meeting, Volume III, pp. 359–368, October 28 - November 1, 1991, CPIA pub. 573.Google Scholar
32. “Combustion Calculations for Composite Solid Propellants”, Beckstead, M.W., Proceedings of the 13th JANNAF Combustion Meeting, Vol. II, p 299 (1976), CPIA publication 281.Google Scholar
33. “Nitramine Composite Solid Propellant Modeling”, Blomshield, F.S., NWC TP-6992 (1989).Google Scholar
34. “The Deflagration of Solid Propellant Oxidizers”, McHale, Edward T. and Elbe, Guenther von, Comb. Sci. Tech. 2, pp. 227–237 (1970).Google Scholar