Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-23T16:19:02.447Z Has data issue: false hasContentIssue false
  • English
  • Français

Solid Oxide Fuel Cells based on Proton Conducting Electrolytes

Published online by Cambridge University Press:  26 February 2011

U. Balachandran ,
Tae H Lee ,
Beihai Ma  and
Stephen E Dorris
U. Balachandran
Affiliation:
[email protected], Argonne National Laboratory, Energy Systems Division, Building 212, 9700S. Cass avenue, Argonne, IL, 60439, United States
Tae H Lee
Affiliation:
[email protected], Argonne National Laboratory, Energy Systems Division, Argonne, IL, 60439, United States
Beihai Ma
Affiliation:
[email protected], Argonne National Laboratory, Energy Systems Division, Argonne, IL, 60439, United States
Stephen E Dorris
Affiliation:
[email protected], Argonne National Laboratory, Energy Systems Division, Argonne, IL, 60439, United States
Get access

Abstract

We have fabricated a solid oxide fuel cell (SOFC) using BaCe0.8Y0.2Ox (BCY) proton conductor as the electrolyte. An ≈ 15-μm-thick dense BCY film was prepared on a porous Ni/BCY cermet (i.e., ceramic/metal composite) substrate by a colloidal spray deposition technique. The gas permeable Ni/BCY cermet substrate backed with nickel mesh was used as the anode, and platinum paste backed with platinum mesh served as cathode. The current-voltage characteristics of the BCY-based SOFC were measured in the temperature range 600-800°C using wet air on the cathode side and wet hydrogen on the anode side. The open circuit voltage was close to the theoretical value at all operating temperatures. The power density of the fuel cell was ≈240 and ≈875 mW/cm2 at 600 and 800°C, respectively.

Keywords

ionic conductorfilmceramic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 972: Symposium AA – Solid-State Ionics—2006 , 2006 , 0972-AA01-09
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Iwahara, H., Uchida, H., and Tanaka, S., J. Appl. Electrochem. 16 (1986) 663.Google Scholar
2. Iwahara, H., Solid State Ionics 28– 30 (1988) 573.Google Scholar
3. Iwahara, H., Uchida, H., and Morimoto, K., J. Electrochem. Soc. 137 (1990) 462.Google Scholar
4. Bonanos, N., Ellis, B., and Knight, K.S., Solid State Ionics 44 (1991) 305.Google Scholar
5. Iwahara, H., Yajima, T., Hibino, T., and Ushida, H., J. Electrochem. Soc. 140 (1993) 1687.Google Scholar
6. Iwahara, H., Solid State Ionics 77 (1995) 289.Google Scholar
7. Bonanos, N., Knight, K.S., and Ellis, B., Solid State Ionics 79 (1995) 161.Google Scholar
8. Taniguchi, N., Yasumoto, E., and Gamo, T., J. Electrochem. Soc. 143 (1996) 1886.Google Scholar
9. Lee, T.H., Dorris, S.E., and Balachandran, U., Solid State Ionics 176 (2005) 1479.Google Scholar
10. Lee, T.H., Harder, B., Zuo, C., Dorris, S.E., and Balachandran, U., Proc. of the 2004 Fall Materials Research Society, Boston, MA, Nov. 29-Dec. 3, (2004).Google Scholar
11. Pham, A., Lee, T.H., and Glass, R.S., Proc. 6th Int. Symp. on Solid Oxide Fuel Cells, Electrochem. Soc. PV 99– 19 (1999) 172.Google Scholar
12. Pham, A., Glass, R., and Lee, T.H., U.S. Patent, No. 6,358,567 (2002).Google Scholar