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Soft Actuators based on Polypyrrole and Polyaniline Composite Films

Published online by Cambridge University Press:  01 February 2011

Keiichi Kaneto  and
Wataru Takashima
Keiichi Kaneto
Affiliation:
[email protected], Kyushu Institute of Technology, LSSE, 2-4, Hibikino,, Wakamatsu, Kitakyushu, Fukuoka, 808-0196, Japan, +81-93-695-6042, +81-93-695-6012
Wataru Takashima
Affiliation:
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu 808-0196, Japan
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Abstract

Elongation and contraction of polypyrrole and poly(3-methoxyaniline-5-sulfonate) (PMAS) composite films induced upon electrochemical oxidation and reduction, viz., electrochemomechanical deformation (ECMD) are studied. The composite films were electrochemically prepared in electrolyte solutions of pyrrole and dodecylbenzene sulfonic (DBS) acid with a presence of PMAS acid. The contents of DBS and PMAS were varied. Films which were obtained at higher contents of PMAS, were gel like due to a lot of water content. The change of film length due to ECMD was measured as functions of various electrolytes in either aqueous or organic solvents. The results indicated that films exhibited both cathodic and anodic expansions depending on the bulkiness of cations and anions as well as the content of PMAS.

Keywords

polymerelectrodepositiondevices
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 889: Symposium W – Electroresponsive Polymers and Their Applications , 2005 , 0889-W03-05
Copyright
Copyright © Materials Research Society 2006

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References

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