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Site Selective Electrodeposition of Metals and Conductive Polymer Nano-Structures on Isolated Carbon Nanopipes Using Electric Fields

Published online by Cambridge University Press:  21 March 2011

Jean-Claude Bradley
Affiliation:
Department of Chemistry, Drexel University, 32nd and Chestnut Streets, Philadelphia, PA 19104, U.S.A
Sundar Babu
Affiliation:
Department of Chemistry, Drexel University, 32nd and Chestnut Streets, Philadelphia, PA 19104, U.S.A
Patrick Ndungu
Affiliation:
Department of Chemistry, Drexel University, 32nd and Chestnut Streets, Philadelphia, PA 19104, U.S.A
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Abstract

We report the successful application of bipolar electrochemistry for depositing metals and conducting polymer nano-structures on isolated template-grown carbon nanopipes (CVD-CNP). Metals such as tin, cobalt and nickel were reduced electrochemically at the tips of isolated CVD- CNP from their chloride or nitrate salts. Polypyrrole dendrites could also be grown on both ends of selected CVD-CNP. The potential applications of thus encapsulated CVD-CNP in nano- fluidics and other areas will be discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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References

1. Dunsch, L., Janda, P., Mukhopadhyay, K., and Shinohara, H.. New Diamond and Frontier Carbon Technology, 11(2), 427 (2001).Google Scholar
2. Austin, D. W., Puretzky, A. A., Geohegan, D. B., Britt, P. F., Guillorn, M. A., and Simpson, M. L., Chem. Phys. Lett. 361, 525 (2002).Google Scholar
3. Hughes, M., Shaffer, M. S. P., Renouf, A. C., Singh, C., Chen, G. Z., Fray, D. J., and Windle, A. H., Adv. Mater. 14, 382 (2002).Google Scholar
4. Chen, X. H., Peng, J. C., Li, X. Q., Deng, F. M., Wang, J. X., and Li, W. Z., J. Mater. Sci. Lett. 20, 2057 (2001).Google Scholar
5. Bradley, J.-C., Babu, S., Carroll, B., and Mittal, A., J. Electroanal. Chem. 522, 75 (2002).Google Scholar
6. Bradley, J.-C., Babu, S., Carroll, B., Mittal, A. and Ndungu, P., J. Electrochem. Soc. 148, C647 (2001)Google Scholar
7. Che, G., Lakshmi, B. B., Martin, C. R., and Fisher, E. R., Chem. Mater. 10, 260 (1998).Google Scholar
8. Bradley, J.-C., Babu, S., Ndungu, P., Nikitin, A., and Gogotsi, Y., ChemWeb Preprint Server, CPS: chemistry/0303002, 2003, http://preprint.chemweb.com/chemistry/0303002Google Scholar
9. Bradley, J.-C., Ndungu, P., and Babu, S., ChemWeb Preprint Server, CPS: chemistry/0304001, 2003, http://preprint.chemweb.com/chemistry/0304001Google Scholar
10. Bradley, J.-C., Ndungu, P., and Babu, S., ChemWeb Preprint Server, CPS: chemistry/0304002, 2003, http://preprint.chemweb.com/chemistry/0304002Google Scholar
11. Bradley, J.-C., Ndungu, P., Babu, S., Tromp, J., and Hackett, N., ChemWeb Preprint Server, CPS: chemistry/0309001, 2003, http://preprint.chemweb.com/chemistry/0309001Google Scholar
12. Bradley, J.-C., Ndungu, P., Babu, S., Tromp, J., and Hackett, N., ChemWeb Preprint Server, CPS: chemistry/0308001, 2003, http://preprint.chemweb.com/chemistry/0308001Google Scholar
13. Bradley, J.-C., Ma, Z., Christaffer, Z., Crawford, J., Emazarova, K., and Stephens, S. G., Semiconductive Polymers, edited by Hseih, B. R. and Wei, Y., 375, ACS Symposium Series Washington, DC. pp. 429 (1999)Google Scholar
14. Fleischmann, M., Ghoroghchian, J., and Pons, S., J. Phys. Chem. 89, 5530 (1985).Google Scholar
15. Eardley, D. C., Handley, D., and S. Andrew, P. S., Electrochim. Acta. 18, 839 (1973)Google Scholar
16. Devers, T., Kante, I., Allam, L., and Fleury, V., J. Non-Cryst. Solids. 321(1-2), 73 (2003)Google Scholar