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Silicon-based Micro Platforms for Characterization of Nanostructured Layers With Application in Intermediate Temperature Micro Solid Oxide Fuel Cells

Published online by Cambridge University Press:  01 February 2011

Inigo Garbayo
Affiliation:
Albert Tarancón
Affiliation:
[email protected], Catalonia Institute for Energy Research (IREC), Barcelona, Spain
José Santiso
Affiliation:
[email protected], Research Center in Nanoscience and Nanotechnology, CIN2, CSIC/ICN, Bellaterra, Spain
Andrea Cavallaro
Affiliation:
[email protected], Research Center in Nanoscience and Nanotechnology, CIN2, CSIC/ICN, Bellaterra, Spain
Isabel Gràcia
Affiliation:
[email protected], National Institute of Microelectronics, IMB-CNM (CSIC), Bellaterra, Spain
Carles Cané
Affiliation:
[email protected], National Institute of Microelectronics, IMB-CNM (CSIC), Bellaterra, Spain
Neus Sabaté
Affiliation:
[email protected], National Institute of Microelectronics, IMB-CNM (CSIC), Bellaterra, Spain
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Abstract

The present work is devoted to study the development of yttria-stabilized zirconia membranes self-supported on silicon-based microplatforms, to be used as electrolytes on micro solid oxide fuel cells. The microfabrication process to obtain yttria-stabilized zirconia membranes is detailed, and some key aspects for the integration of yttria-stabilized zirconia films deposited by pulsed laser deposition on the silicon-based microplatform are shown. Moreover, the effect on the thermomechanical stability of different fabrication parameters is presented, as well as the way to control the pinhole generation on the membranes. Finally, some electrical characterization guidelines are included, in order to study the effects of the platform and the membrane dimensions on the different measurements performed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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References

1 Kundu, A. Jang, J.H. Gil, J.H. Jung, C.R. Lee, H.R. Kim, S.H. Ku, B. and Oh, Y.S. J. Power Sources 170 (2007) 67.Google Scholar
2 Hertz, J.L. Lappalanien, J. Kek, D. Stefanik, T. and Tuller, H.L.J., Electrochem. Soc. Proc. 25 (2002) 137.Google Scholar
3 Shao, Z.P. Haile, S.M. Ahn, J. Ronney, P.D. Zhan, Z.L. and Barnett, S.A., Nature 435 (2005) 795.Google Scholar
4 Nikbin, D. The Fuel Cell Review 3 (2006) 21.Google Scholar
5 Evans, A. Bieberle-Hütter, A. Rupp, J.L.M., Gauckler, L.J. J. Power Sources 194 (2009) 119.Google Scholar
6 Bieberle-Hütter, A. Beckel, D. Infortuna, A. Muecke, U. Rupp, J. Gauckler, L. Rey-Mermet, S., Muralt, P. Bieri, N. Hotz, N. Stutz, M. Poulikakos, D. Heeb, P. Müller, P. Bernard, A. Gmür, R. and Hocker, T. J. Power Sources 177 (2008) 123.Google Scholar
7 Muecke, P. Beckel, D. Bernard, A. Bieberle-Hütter, A. Graf, S. Infortuna, A. Müller, P. Rupp, J.L.M., Schneider, J. Gauckler, L.J. Adv. Funct. Mater. 18 (2008) 1.Google Scholar
8 Shim, J.H. Chao, C.C. Huanga, H. Prinz, F.B. Chem. Mater. 19 (2007) 3850.Google Scholar
9 Su, P.C. Chao, C.C. Shim, J.H. Fasching, R. Prinz, F.B. Nano Lett. 8 (2008) 2289.Google Scholar
10Tarancón, A. Sabaté, N., Cavallaro, A. Gràcia, I. Roqueta, J. Garbayo, I. Esquivel, J.P. Garcia, G. Cané, C., Santiso, J. J. Nanosc. Nanotechnol 10 (2010) 1.Google Scholar
11 Garbayo, I. Tarancón, A. Santiso, J. Peiró, F., Alarcón-LLadó, E., Cavallaro, A. Gràcia, I. Cané, C., Sabaté, N., Solid State Ionics 181 (2010) 322.Google Scholar
12 Ziebart, V. Paul, O. and Baltes, H. J. Microelectromechanical Systems 8, 4 (1999)Google Scholar
13 Lakki, A. Herzog, R. Weller, M. Schubert, H. Reetz, C. Görke, O. Kilo, M. Borchardt, G. J. Eur. Ceram. Soc. 20 (2000) 285.Google Scholar
14 Goodenough, J.B. Annu. Rev. Mater. Res. 33 (2003) 91.Google Scholar
15 Johnson, A.C. Lai, B.-K., Xiong, H. Ramanathan, S. J. Power Sources 186 (2009) 252.Google Scholar