Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-17T17:00:45.564Z Has data issue: false hasContentIssue false

Silicon on Sapphire of Single Crystal Quality Obtained by Double Solid Phase Epitaxial Regrowth

Published online by Cambridge University Press:  26 February 2011

M. A. Parker
Affiliation:
Materials Science Dept., Stanford University, Stanford, CA 94305
R. Sinclair
Affiliation:
Materials and Process Engineering Dept., IBM, Rochester, MN 55901
T. W. Sigmon
Affiliation:
Electrical Engineering Dept., Stanford University, Stanford, CA 94305
Get access

Abstract

A dual-implantation and annealing procedure has been refined which results in silicon films of single crystal perfection on sapphire substrates. This double solid phase epitaxy (DPSE) procedure consists of two self-implantation steps that serve to amorphize the defect structure of the parent silicon film with subsequent annealing steps employed to recrystallize the amorphized structure. High resolution cross-section transmission electron microscopy (HRXTEM) and ion channeling have been employed to study the microstructure of the silicon films, the sapphire substrates, and the interface. The resulting perfection of the silicon layer is shown to be a sensitive function of the first self-implant energy, dose, and silicon film thickness. Also, a correlation has been established between microtwin density and dechanneling profiles. HRXTEM of microtwins in silicon on sapphire (SOS) starting material demonstrates contrast features identified as rotational Moire' fringes between the microtwins and the matrix by means of optical diffractometry. Best results are achieved for the first implant energy of 170 keV 28Si+. Thus, the DSPE process is shown to give optimal results in defect reduction.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Cullen, G. W., ”The preparation and properties of chemically vapor deposited silicon on sapphire and spinel.”; Proc. 1st Intl. Conf. on Crystal Growth and Epitaxy from the Vapor Phase, Zurich, 107 (1970).Google Scholar
2. Christel, L. A., Reedy, R. E., and Sigmon, T. W., Appl. Phys. Lett., 42, 707 (1983).Google Scholar
3. Yoshii, T., Taguchi, S., Inoue, T. and Tango, H., Japan. J. Appl. Phys., 21 (Supl. 21–1), 175 (1982).Google Scholar
4. Bravman, J. and Sinclair, R., Jour. Elec. Micro. Techs., 1, 53 (1984).Google Scholar
5. Carey, K. A. W., Silicon on Sapphire: An Investigation of the Defect Structure, Ph.D.Thesis, Stanford (1981).Google Scholar
6. Chapelle, T. J. La, Miller, A. and Morritz, F. L., Prog. Solid State Chem., 3, 1 (1964).Google Scholar
7. Abrahams, M. S. and Buiocchi, C. J., Appl. Phys. Lett., 27, 325 (1975).10.1063/1.88487Google Scholar
8. Ponce, F. A., Defects in Semiconductors, edited by Narayan, J. and Tan, T.Y. (North-Holland, New York, 1980), pg. 285.Google Scholar
9. Amano, J., Aranovich, J., Carey, K. W. and Ponce, F. A., J. Appl. Phys. 54, 4414 (1983).Google Scholar
10. Hutchinson, J. L., Booker, G. R. and Abrahams, M. S., Microscopy of Semiconducting Materials 1981, edited by Cullis, A. G. and Joy, D. C. (Institute of Physics, London, 1981), p. 139.Google Scholar
11. Smith, D. J., Freeman, L. A., McMahon, R. A., Ahmed, H., Pitts, M. G. and Peters, T. B., J. Appl. Phys., 56, 2207 (1984).CrossRefGoogle Scholar
12. Parker, M. A., Sigmon, T. W. and Sinclair, R., Appl. Phys. Lett., submitted.Google Scholar
13. Hirsch, P., Howie, A., Nicholson, R. B., Pashley, D. W. and Whelan, M. J., Electron Microscopy of Thin Crystals, Krieger, New York 1977.Google Scholar
14. Spence, J. C. H., Experimental High-Resolution Electron Microscopy, Clarendon Press, Oxford 1981.CrossRefGoogle Scholar