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Silicide engineering: influence of alloying elements on CoSi2 nucleation
Published online by Cambridge University Press: 14 March 2011
Abstract
Evidence is presented that the nucleation of CoSi2 can be influenced by the presence of small amounts of other elements. The presence of trace amounts of Ti in the CoSi (originating from either a Ti capping layer or interlayer) causes an increase in the CoSi2 nucleation temperature. Moreover, the presence of Ti in the CoSi induces a preferential orientation of the CoSi2 : for an increasing amount of Ti, we observed a transition from polycrystalline CoSi2 over preferential (220) orientation towards epitaxial (400) CoSi2. We observed similar effects for other elements (e.g. Ta, W, C, Mo, Cr). We were able to explain these findings based on the heterogeneous nucleation of CoSi2.
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- Copyright © Materials Research Society 2000
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