Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-27T02:16:13.237Z Has data issue: false hasContentIssue false

Silane Discharge Gas and Surface Reactions

Published online by Cambridge University Press:  21 February 2011

Alan Gallagher*
Affiliation:
Joint Institute for Laboratory Astrophysics, University of Colorado and National Bureau of Standards, Boulder, Colorado 80309 USA
Get access

Abstract

In order to control the quality and properties of hydrogenated amor-phous silicon (a–Si:H) semiconductors produced by discharge deposition, we would like to control the gas species produced in the discharge and to understand how these deposit and influence the film properties. One would like to separately consider the gas processes that yield the mix of species arriving at the surface, and then the surface processes. I will somewhat follow that separation here, but it appears that many of the species found in the gas may, in fact, be released from the surface. Thus, the gas species appear to result from gas and surface reactions, and a sequential separation is actually not possible. Similarly, the study of the surface deposition process requires forming various radical species as well as an a–Si:H surface, which inevitably will involve the gas processes. Thus we really have coupled problems.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Long, W. H., Jr., Tech. Report AFAPL-TR-76-2038 (1979).Google Scholar
2. Boeuf, J. P. and Marode, E., J. Phys. D: Appl. Phys. 15, 2169 (1982).Google Scholar
3. Ohuchi, M. and Kubota, T., J. Phys. D: Appl. Phys. 16, 1705 (1983).Google Scholar
4. Kushner, M. J., J. Appl. Phys. 54, 4958 (1983).CrossRefGoogle Scholar
5. Carlson, D. E., et al., Quarterly Report #1 for Oct. I - Dec. 31, 1980under contract XG-0-9372-1, RCA Laboratory, Princeton, NJ 08540.Google Scholar
6. Chatham, H. and Gallagher, A., “Ion Chemistry in Silane dc Discharges,” to be published.Google Scholar
7. Gallagher, A. and Scott, J., Final Report (Feb. 19, 1980- April 14, 1981), contract XJ-0-9053-1, University of Colorado, Boulder, CO 80309.Google Scholar
8. Gallagher, A. and Scott, J., Final report (April 15, 1980- April 14, 1981), contract XB-2-02189-1, University of Colorado, Boulder, CO 80309.Google Scholar
9. Longeway, P. A., Weakliem, H. A. and Estes, R. D., J. Phys. Chem. 88, 3282 (1984).Google Scholar
10. Tachibana, K., Tadokoro, H. and Urano, Y., J. Phys. D: Appl. Phys. 15, 177 (1982).Google Scholar
11. Schmitt, J. P. M., Gressier, P., Kirshnan, M., de Rosny, G. and Perrin, J., Chem. Phys. 84, 281 (1984).CrossRefGoogle Scholar
12. Jasinski, J. M., Whittaker, E. A., Bjorklund, G. C., Dreyfus, R. W., Estes, R. D. and Walkup, R. E., Appl. Phys. Lett. 44, 1155 (1984).Google Scholar
13. Robertson, R., Hils, D., Chatham, H. and Gallagher, A., Appl. Phys. Lett. 43, 544 (1983).Google Scholar
14. Baiocchi, F. A., Wetzel, R. C. and Freund, R. S., Phys. Rev. Lett. 53, 771 (1984).CrossRefGoogle Scholar
15. de Rosny, G., Mossberg, E., Jr., Abelson, J., Devaud, G. and Kerns, R., J. Appl. Phys. 54, 2272 (1983).Google Scholar
16. Perrin, J., Schmitt, J. P. M., de Rosny, G., Drevillon, B., Huc, J. and Lloret, A., Chem. Phys. 73, 383 (1982).CrossRefGoogle Scholar
17. Winters, R. F., J. Chem. Phys. 63, 3462 (1975).Google Scholar
18. Melton, C. E. and Rudolf, P. S., J. Chem. Phys. 47, 1771 (1967).Google Scholar
19. Robertson, R., Hils, D. and Gallagher, A., Chem. Ph-ys. Lett. 103, 397 (1984).Google Scholar