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SEM Study of Chemical Variations in Western U.S. Fly Ash

Published online by Cambridge University Press:  25 February 2011

Robert J. Tevenson
Affiliation:
North Dakota Mining and Mineral Resources Research Institute, University of North Dakota, Grand Forks, ND 58202.
Timothy P. Huber
Affiliation:
North Dakota Mining and Mineral Resources Research Institute, University of North Dakota, Grand Forks, ND 58202.
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Abstract

Scanning electron microscope/electron microprobe chemical analyses of individual grains of several western fly ashes have shown an inter-grain variation in composition for ashes derived from both lignite and subbituminous western coals. SRM 2689 (a Class F fly ash from a bituminous coal) and SRM 2691 (a Class C fly ash from a subbituminous coal) have been included in the study and also show inter-grain chemical variation. A classification scheme of fly ash grain compositions has been developed and has proven to be useful in illustrating the differences and similarities of the ashes. There is a positive correlation, for example, between grains rich in SiO2 and Al2O3 and the Na2O content of the grains in lignite and subbituminous coal derived fly ashes. There is also a positive correlation between grains rich in CaO and the MgO content of the grains in both classes of fly ashes.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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References

REFERENCES

1. Stevenson, R.J., Cem. Concr. Res. 14, 485490 (1984).Google Scholar
2. Stevenson, R.J. and Larson, R.A., in Fly Ash and Coal Conversion By-Products: Characterization, Utilization and Disposal I, edited by McCarthy, G.J. and Lauf, R.J., Mat. Res. Soc. Symp. Proc. Vol.43, (Materials Research Society, Pittsburgh, 1985) pp. 177186.Google Scholar
3. Stevenson, R.J. and McCarthy, G.J., in Fly Ash and Coal Conversion By- Products: Characterization, Utilization and Disposal II, edited by McCarthy, G.J., Glasser, F.P. and Roy, D.M., Mat. Res. Soc. Symp. Proc. Vol.65, (Materials Research Society, Pittsburgh, 1986) pp. 7790.Google Scholar
4. Kanare, H.M., in Fly Ash and Coal Conversion By-Products: Characterization, Utilization and Disposal II, edited by McCarthy, G.J., Glasser, F.P. and Roy, D.M., Mat. Res. Soc. Symp. Proc. Vol.65 (Materials Research Society, Pittsburgh, 1986) pp. 159160.Google Scholar
5. McCarthy, G.J., Manz, O.E., Stevenson, R.J., Hassett, D.J. and Groenewold, G.H. in Fly Ash and Coal Conversion By-Products: Characterization, Utilization and Disposal II, edited by McCarthy, G.J., Glasser, F.P. and Roy, D.M., Mat. Res. Soc. Symp. Proc. 65, (Materials Research Society, Pittsburgh, 1986) pp. 165166.Google Scholar
6. Bence, A.E. and Albee, A., J. Geol. 76, 382403 (1968).Google Scholar
7. Hemmings, R.T. and Berry, E.E., in Fly Ash and Coal Conversion By-Products: Characterization, Utilization and Disposal II, edited by McCarthy, G.J., Glasser, F.P. and Roy, D.M., Mat. Res. Soc. Symp. Proc. Vol.65 (Materials Research Society, Pittsburgh, 1986) pp. 91104.Google Scholar
8. Karner, F.R., Benson, S.A., Schobert, H.H. and Roaldson, R.G., in The Chemistry of Low Rank Coals, edited by Schobert, H.H., ACS Symp. Ser. 264, (American Chemical Society, Washington, 1984), pp. 175193.Google Scholar
9. Lauf, R.J., Am. Ceramic Soc. Bull. 61, 487490 (1982).Google Scholar