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Self-Organized Hybrid Solids

Published online by Cambridge University Press:  01 February 2011

Joël J.E. Moreau ,
Luc Vellutini ,
Michel Wong Chi Man ,
Catherine Bied ,
Jean-Louis Bantignies ,
Philippe Dieudonné  and
Jean-Louis Sauvajol
Joël J.E. Moreau
Affiliation:
Hétérochimie Moléculaire et Macromoléculaire (UMR-CNRS 5076), Ecole Normale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier Cedex 05 (France).
Luc Vellutini
Affiliation:
Hétérochimie Moléculaire et Macromoléculaire (UMR-CNRS 5076), Ecole Normale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier Cedex 05 (France).
Michel Wong Chi Man
Affiliation:
Hétérochimie Moléculaire et Macromoléculaire (UMR-CNRS 5076), Ecole Normale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier Cedex 05 (France).
Catherine Bied
Affiliation:
Hétérochimie Moléculaire et Macromoléculaire (UMR-CNRS 5076), Ecole Normale Supérieure de Chimie de Montpellier, 8, rue de l'école normale, 34296 Montpellier Cedex 05 (France).
Jean-Louis Bantignies
Affiliation:
Groupe de Dynamique des Phases Condensées (UMR-CNRS 5581), Université Montpellier II, Place Eugène Bataillon, 34095 Montpellier Cedex 05 (France)
Philippe Dieudonné
Affiliation:
Groupe de Dynamique des Phases Condensées (UMR-CNRS 5581), Université Montpellier II, Place Eugène Bataillon, 34095 Montpellier Cedex 05 (France)
Jean-Louis Sauvajol
Affiliation:
Groupe de Dynamique des Phases Condensées (UMR-CNRS 5581), Université Montpellier II, Place Eugène Bataillon, 34095 Montpellier Cedex 05 (France)
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Abstract

A new method has been developed for the synthesis of shaped-controlled bridged silsesquioxanes by the acid hydrolysis of urea-derived silylated precursors. This method is based on the ability of the hydrogen bonds of the urea groups to organize the molecules in a supramolecular architecture and provides after hydrolysis a new access to hybrid materials with controlled morphologies. A chirality transcription from a molecular precursor to a hybrid solid has been achieved. A right- and a left-handed helices have been obtained respectively from the chiral (R,R)- and the (S,S)-enantiomers of the diureido derivatives of trans-diaminocyclohexane. In a related way, a long range ordered hybrid solid has been obtained. Long carbon chain as spacer between the urea groups of the precursor affords lamellar hybrid silicas.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 726: Symposium Q – Hybrid Organic-Inorganic Materials , 2002 , Q7.2
Copyright
Copyright © Materials Research Society 2002

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