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Selective Deposition of Two-Dimensional Colloidal Arrays on Patterned Polyelectrolyte Multilayer Templates

Published online by Cambridge University Press:  17 March 2011

Haipeng Zheng ,
Ilsoon Lee ,
Michael F. Rubner  and
Paula T. Hammond
Haipeng Zheng
Affiliation:
Department of Chemical Engineering and Department of Materials Science and Engineering, The Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139, U.S.A
Ilsoon Lee
Affiliation:
Department of Chemical Engineering and Department of Materials Science and Engineering, The Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139, U.S.A
Michael F. Rubner
Affiliation:
Department of Chemical Engineering and Department of Materials Science and Engineering, The Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139, U.S.A
Paula T. Hammond
Affiliation:
Department of Chemical Engineering and Department of Materials Science and Engineering, The Microphotonics Center, Massachusetts Institute of Technology, Cambridge, MA 02139, U.S.A
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Abstract

A new method for the patterning of colloidal particles on polymer templates is presented. A polyelectrolyte multilayer film is deposited onto a chemically patterned monolayer surface, which is further used as a functional template to direct the deposition of charged particles through electrostatic and secondary interactions. After modified by an opposite charged surfactant, the particles change their deposition selectivity from the polyelectrolyte surface to a neutral ethylene glycol monolayer surface. Based on the different selectivity, we have first demonstrated a new approach to direct two component colloidal arrays onto a patterned polyelectrolyte multilayer template.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 694: Symposium K – Microphotonics 2001–Materials, Physics and Applications , 2001 , K3.7
Copyright
Copyright © Materials Research Society 2002

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