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Selective Deposition of Polycrystalline Silicon Thin Films by Hot-Wire CVD
Published online by Cambridge University Press: 15 February 2011
Abstract
Polycrystalline silicon thin films have been selectively deposited at a deposition rate of 60–100Å/min and a substrate temperature of 300°C on molybdenum or silicon over silicon dioxide, silicon nitride or Coming 7059 glass substrate in a continuous hot-wire CVD process involving hydrogen and disilane. Excellent selectivity is achieved on features as small as one micrometer spaced molybdenum lines. The crystallinity of the selectively deposited polysilicon films is thickness dependent. The substrate selectivity is sensitive to both silicon content in the gas phase and substrate temperature. Selective deposition shifts to lower Si content in the gas phase when substrate temperature increases. At a certain substrate temperature, for a silicon content above a certain value in the gas phase, films with similar crystallinity are non-selectively deposited on both molybdenum and silicon dioxide.
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