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Selective Area Omvpe Growth of GaInP on Patterned GaAs Substrates Using Semimetallic Amorphous Carbon Mask

Published online by Cambridge University Press:  21 February 2011

Keith L. Whittingham
Affiliation:
OMVPE Facility, School of Electrical Engineering, Cornell University, Ithaca, NY 14853
Bobby L. Pitts
Affiliation:
OMVPE Facility, School of Electrical Engineering, Cornell University, Ithaca, NY 14853
Gregory F. Redinbo
Affiliation:
School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853
James R. Shealy
Affiliation:
OMVPE Facility, School of Electrical Engineering, Cornell University, Ithaca, NY 14853
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Abstract

In this study, we have investigated the effectiveness of semimetallic, amorphous carbon films as a liftoff mask in the selective growth, by OMVPE, of GaInP epitaxial layers, on (001) oriented GaAs substrates. Scanning electron microscopy, cathodoluminescence spectroscopy and EDX analysis have been employed to characterize the epitaxial material. Our results show excellent selectivity with little nucleation taking place on the amorphous carbon mask in the region of the patterned openings. Liftoff of the carbon mask was very easily achieved, leaving no unintentional nucleation on the substrate below. Investigations in the AlGaAs/GaAs system did not yield the same degree of selectivity with this mask, but the polycrystalline film that deposited on the mask was cleanly lifted from the substrate by the liftoff of the mask.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

1 Galeuchet, Y.D., Roentgen, P. and Graf, V., J. Appl. Phys. 68,560 (1990).Google Scholar
2 Keyser, O., J. Cryst. Growth. 107,989 (1991).Google Scholar
3 Guimarães, F.E.G.,Eisner, B.,R.Westphalen, ,Spangenberg, B.,H.J.Geelen, ,Heime, P. BalkandK., J. Cryst. Growth. 124,199 (1992).Google Scholar
4 Keyser, O.,Westphalen, R., Opitz, B. and Balk, P., J. Cryst. Growth. 112, 111 (1991).Google Scholar
5 Bhat, R., J. Cryst. Growth. 120,362 (1992).Google Scholar
6 C, Caneau, Bhat, R., Frie, M.R., Chang, C.C., Deri, R.J. and Koza, M.A., J. Cryst. Growth. 124,243 (1992).Google Scholar
7 Ogura, M., Chen, Z.Y., Kaneko, H., Fujii, S., Itoh, H., Watanabe, M., Mukai, S. and Yajima, H., Appl. Phys. Lett. 62, 3417 (1993).Google Scholar
8 Maassen, M., Kayser, O., Westphalen, R., Guimarães, F., Geurts, J., Finders, J. and Balk, P., J. Elect. Mater. 21, 257 (1992).Google Scholar
9 Joyner, C.H., Chandrasekhar, S., Sulhoff, J.W. and Dentai, A.G., IEEE Phot. Tech. Lett. 4, 1006 (1992).Google Scholar
10 Porkolab, G.A. and Wolf, E.D., J. Vac. Sci. Technol. B10, 2681 (1992).Google Scholar
11 Purser, R.G., Strane, J.W. and Mayer, J.W. in, Materials Reliability in Microelectronics, edited by Rodbel, K., Filter, B., Ho, P. and Frost, H. (Mater. Res. Soc. Proc. Pittsburgh, PA, 1993) pp. 481.Google Scholar
12 Pitts, B.L., Emerson, D.T., Matragrano, M.J. and Shealy, J.R., 20th Int’l Symp. on GaAs and Rel. Mater., Frieberg, Germany, 1993 (unpublished).Google Scholar
13 Chen, G.S. and Stringfellow, G.B., Appl. Phys. Lett. 59,324 (1991).Google Scholar
14 Lee, M.K., Horng, R.H. and Haung, L.C., J. Cryst. Growth 124, 358 (1992).Google Scholar
15 S.W.MacLaren, ,Baker, J.E., N.L.Finnegan, and Loxton, CM. J. Vac. Sci. Technol. A 10,486 (1992).Google Scholar