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The Role of Sei in Lithium and Lithium Ion Batteries

Published online by Cambridge University Press:  15 February 2011

E. Peled ,
D. Golodnttsky ,
G. Ardel ,
C. Menachem ,
D. Bar Tow  and
V. Eshkenazy
E. Peled
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
D. Golodnttsky
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
G. Ardel
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
C. Menachem
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
D. Bar Tow
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
V. Eshkenazy
Affiliation:
School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel
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Abstract

This paper presents and discusses fundamental processes taking place at the lithium and LixC6 electrode/electrolyte interphases and models for these interphases. We deal with both nonaqueous and polymer (dry and gel) electrolytes, graphitized and nongraphitized carbonaceous materials as anodes for Li-ion batteries. Each electrode/electrolyte combination has its own unique features and problems but there are some general phenomena common to all of them. Issues to be reviewed include SEI composition, morphology and formation reactions, graphite surface modifications including chemical bonded SEI and micro channels formation, electrode degradation processes, lithium deposition-dissolution and intercalation-deintercalation mechanisms, rate-determining steps (RDS), electrolyte and electrode parameters and conditions affecting the above mentioned processes. Technologyrelated issues are emphasized.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 393: Symposium W – Materials for Electrochemical Energy Storage and Conversion , 1995 , 209
Copyright
Copyright © Materials Research Society 1995

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References

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