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The Role of Metal Ion Solubility in Leaching of Nuclear Waste Glasses*

Published online by Cambridge University Press:  15 February 2011

B. Grambow
B. Grambow*
Affiliation:
Pacific Northwest Laboratory, P. O. Box 999, Richland, Washington 99352, USA and Hahn-Meitner-Institut fűr Kernforschung Berlin GmbH, 1000 Berlin 39 Glienicker Str. 100, Berlin, Germany
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Extract

The leachability of solid nuclear waste forms has been studied by many investigators to evaluate the short-term kinetics of elemental release or to determine the effects of leachant composition or other system parameters. Some general observations from these studies have included: incongruent leaching; formation of reaction layers that contain rare-earth, alkaline-earth, or transition metal elements; and apparent saturation of some elements in solution while others continue to be leached. Before these observations can be used to predict long-term performance of waste glasses under repository conditions, the mechanisms controlling the release of elements from the solid must be understood.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 11: Symposium – Scientific Basis for Nuclear Waste Management V , 1981 , 93
Copyright
Copyright © Materials Research Society 1982

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Footnotes

*

This work was supported by the U.S. Department of Energy under Contract DE-AC06-76RLO 1830.

References

REFERENCES

1. McVay, G.L. and Buckwalter, C.Q., (1980) Nuc. Tech. 51, 123–129.CrossRefGoogle Scholar
2. Clark, D. and Hench, L., (1981) Nuc. and Chem. Waste Management, 2, 93–101.CrossRefGoogle Scholar
3. Strachan, D.M., (1982) Results from a 1-Year Leach Test: Long-Term Use of MCC-1. PNL-SA-10036, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
4. Barkatt, A., Simmons, J. and Macedo, P., (1981) Nuc. and Chem. Waste Management, 2:1, 3–23.CrossRefGoogle Scholar
5. Strachan, D.M., Turcotte, R.P. and Barnes, B.O., (1981) PNL-SA-8737, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
6. Rai, D., (1982) Neptunium Concentration in Solutions Contacting Actinide Doped Glass, Nuc. Tech. PNL-SA-9699, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
7. Materials Characterization Center. (1981) Nuclear Waste Materials Handbook, DOE/TIC-11400, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
8. Buckwalter, C.Q., McVay, G.L., Kuhn, W. and Peters, P., (1982) The Effect of pH on the Leaching of a Nuclear Waste Glass, PNL-SA-10321, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
9. Fullam, H.T., (1981) PNL-3614, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
10. MCC-Materials Characterization Center (1981), PNL-3990, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar
11. Lindsay, W., (1979) Chemical Equilibria in Soil, John Wiley & Sons, New York, USA.Google Scholar
12. Ames, L.L. and Rai, D., (1978) Radionuclide Interactions with Soil and Rock Media, 1, EPA 520/6–78–007–a, PB 292460.Google Scholar
13. Schumm, R., Wagman, D., Bailey, S., Evans, W. and Parker, V., (1973) NBS Technical Note 270–7.Google Scholar
14. Smyshlyaer, S.I. et al. (1977) Sevcro-Karkazskii Nauchnyi Tsentia Vysshei Shkoly Izvestia, 60–63.Google Scholar
15. Chick, L.A., McVay, G.L., Mellinger, G.B. and Roberts, F.P., (1980), PNL-3465, Pacific Northwest Laboratory, Richland, Washington 99352, USA.Google Scholar