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Role of ion exchange in the corrosion of nuclear waste glasses

Published online by Cambridge University Press:  21 March 2011

M.I. Ojovan ,
W.E. Lee  and
R.J. Hand
M.I. Ojovan
Affiliation:
Immobilisation Science Laboratory, Department of Engineering Materials, University of Sheffield, United Kingdom
W.E. Lee
Affiliation:
Immobilisation Science Laboratory, Department of Engineering Materials, University of Sheffield, United Kingdom
R.J. Hand
Affiliation:
Immobilisation Science Laboratory, Department of Engineering Materials, University of Sheffield, United Kingdom
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Abstract

The ion exchange phase of corrosion of nuclear waste glasses was modelled using Doremus' theory of interdiffusion and numerically analysed for British Magnox waste and Russian K-26 glasses. It is shown that even in non-silica -saturated conditions the ion exchange phase plays a significant role in the overall radionuclide release inventory particularly for short-lived radionuclides.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 932: Symposium – Scientific Basis for Nuclear Waste Management XXIX , 2006 , 128.1
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1. Silvestri, A., Molin, G., Salviulo, G.. J. Non-Cryst. Sol., 351, 1338–1349 (2005).Google Scholar
2. Ericson, J.E., Dersch, O., Rauch, F.. J. Archaeological Science, 31, 883–902 (2004).Google Scholar
3. Ojovan, M.I., Hand, R.J., Ojovan, N.V., Lee, W.E.. J. Nucl. Mat. 340, 12–24 (2005).Google Scholar
4. Ojovan, M.I., Pankov, A.S., Lee, W.E., Hand, R.J.. Proc. WM'05 Conference, Tucson, Arizona, 11p., 5114.pdf. (2005).Google Scholar
5. Appen, A.A.. Chemistry of glass. Khimiya, Leningrad, 1-352 (1970).Google Scholar
6. Boksay, Z., Bouquet, G., Dobos, S.. Phys. Chem. Glasses, 8, 140–144 (1967).Google Scholar
7. Boksay, Z., Bouquet, G., Dobos, S.. Phys. Chem. Glasses, 9, 69–71 (1968).Google Scholar
8. Doremus, R.H.. J. Non-Cryst. Solids, 48, 431–436 (1982).Google Scholar
9. Agaard, P., Helgeson, H.C.. Am. J. Sci., 282, 237–285 (1982).Google Scholar
10. Bacon, D.H., McGrail, B.P.. Mat. Res. Soc. Symp. Proc. 757, II1.9.1–6 (2003).Google Scholar
11. Abraitis, P.K., Livens, F.R., Monteith, J.E., Small, J.S., Triverdi, D.P., Vaughan, D.J., Wogelius, R.A.. Applied Geochemistry, 15, 1399–1416 (2000).Google Scholar
12. Ebert, W.L.. Phys. Chem. Glasses, 34 (2) 58–65 (1993).Google Scholar
13. Ojovan, M.I., Lee, W.E., Hand, R.J., Ojovan, N.V.. Proc. XX Int. Congress on Glass, sr00700033DIS, Kyoto, Japan, 27.09-1.10.2004.Google Scholar
14. Smets, B.M.J., Tholen, M.G.W.. Phys. Chem. Glasses, 26, 60–63 (1985).Google Scholar
15. Ojovan, M.I., Lee, W.E.. J. Nucl. Mat., 335, 425–432 (2004).Google Scholar
16. Ivanov, I.A., Stefanovsky, S.V., Gulin, A.N.. Glass Phys. Chemistry, 19, 746–755 (1993).Google Scholar
17. Aertsens, M., Lemmens, K., Iseghem, P. Van. Mat. Res. Soc. Proc., 757, II5.8.1–8 (2003).Google Scholar
18. Pankov, A., Ojovan, M.I., Lee, W.E., Scales, C.R.. Proc ICEM'05, ICEM05-1130 (2005).Google Scholar
19. Zoune-Thimm, A.. Doctoral dissertation. J.W. Goethe-Universitat. Frankfurt Main (1999).Google Scholar
20. Inagaki, Y., Idemitsu, K., Arima, T., Maeda, T., Ogawa, H., F. Itonaga. Mat. Res. Soc. Proc., 713, JJ11.55.1–8 (2002).Google Scholar
21. McGrail, B.P., Bacon, D.H., Icenhover, J.P., Mann, F.M., Puigh, R.J., Shaef, H.T., Matigod, S.F.. J. Nucl. Mat., 298, 95–111 (2001).Google Scholar